Mode-division multiplexing (MDM) is an attractive solution for future on-chip networks to enhance the optical transmission capacity with a single laser source. A mode-division reconfigurable optical add/drop multiplexer (ROADM) is one of the key components to construct flexible and complex on-chip optical networks for MDM systems. In this paper, we report on a novel scheme of mode-division ROADM with mode-selective silicon photonic MEMS (micro-electromechanical system) switches. With this ROADM device, data carried by any mode-channels can be rerouted or switched at an MDM network node, i.e., any mode could be added/dropped to/from the multimode bus waveguide flexibly and selectively. Particularly, the design and simulation of adiabatic vertical couplers for three quasi-TE modes (TE0, TE1, and TE2 modes) based on effective index analysis and mode overlap calculation method are reported. The calculated insertion losses are less than 0.08 dB, 0.19 dB, and 0.03 dB for the TE0 mode, TE1 mode, and TE2 mode couplers, respectively, over a wavelength range of 75 nm (1515–1590 nm). The crosstalks are below −20 dB over the bandwidth. The proposed device is promising for future on-chip optical networks with flexible functionality and large-scale integration.