“…Theoretical models of ionization inside hot cavity were extensively studied [69]. Recently, both theoretical [10], and numerical models of ionizations have been developed [11,12] based on the conception that high ionization eciency is an eect of multiple collisions with hot ionizer walls, and also electron impact ionization [13]. The model enabled the studies of ionization eciency as a function of many factors, ionizer geometry (including the spherical one [14]), extraction system properties, ionizer temperature, ionizer/ sample combination etc.…”