2006
DOI: 10.1021/ol061904d
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Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene

Abstract: A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential. [structure: see text]

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Cited by 74 publications
(51 citation statements)
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“…Similar attractive molecular structures are found in compounds like hexakis(4-ferrocenylphenyl)benzene (C 6 -(C 6 H 4 Fc) 6 ), hexakis(ferrocenylethynyl)benzene (C 6 (C CFc') 6 , Fc' = substituted ferrocenyl) and [(FeCp) 3 (trindenyl)]. [5] In 2011, super-crowded ferrocenyl-substituted five-membered heterocycles ( c C 4 Fc 4 X, X = O, S, NR) were added to this family of compounds. [6] Their interesting electronic properties were studied in detail by spectroelectrochemistry.…”
Section: Dedicated To Professor Gerhard Erker In Occasion Of His 65thmentioning
confidence: 56%
“…Similar attractive molecular structures are found in compounds like hexakis(4-ferrocenylphenyl)benzene (C 6 -(C 6 H 4 Fc) 6 ), hexakis(ferrocenylethynyl)benzene (C 6 (C CFc') 6 , Fc' = substituted ferrocenyl) and [(FeCp) 3 (trindenyl)]. [5] In 2011, super-crowded ferrocenyl-substituted five-membered heterocycles ( c C 4 Fc 4 X, X = O, S, NR) were added to this family of compounds. [6] Their interesting electronic properties were studied in detail by spectroelectrochemistry.…”
Section: Dedicated To Professor Gerhard Erker In Occasion Of His 65thmentioning
confidence: 56%
“…To expand the library of possible compounds, 1,2-bis( p-ferrocenylphenyl)acetylene was successfully synthesised (Scheme S1, ESI †) using a route that differs from that published by Rathore et al 17 and subsequently used in a [2 + 4] Diels-Alder cycloaddition with 9 to give tetra-ferrocenyl polyphenylene 12.…”
Section: Synthesis Of Heteroatom-containing Polyphenylenes 10 11 and 12mentioning
confidence: 99%
“…¾hnliche interessante Molekülstrukturen zeigen Verbindungen wie Hexakis(4-ferrocenylphenyl)benzol (C 6 (C 6 H 4 Fc) 6 ), Hexakis(ferrocenylethinyl)benzol (C 6 (C CFc') 6 , Fc' = substituiertes Ferrocenyl) und [(FeCp) 3 (trindenyl)]. [5] Perferrocenylsubstituierte fünf-gliedrige Heterocyclen ( c C 4 Fc 4 X; X = O, S, NR), die erstmals 2011 vorgestellt wurden, sind weitere Beispiele reizvoller Verbindungen. [6] Ihre interessanten elektronischen Eigenschaften wurden intensiv mittels spektroelektrochemischer Messungen untersucht.…”
Section: Professor Gerhard Erker Zum 65 Geburtstag Gewidmetunclassified