Simultaneous laser-induced synthesis and micro-patterning of a metal organic framework

Armon, Nina; Greenberg, Ehud; Edri, Eitan; Kenigsberg, Avraham; Piperno, Serge; Kapon, Omree; Fleker, Ohad; Perelshtein, Ilana; Cohen‐Taguri, Gili; Hod, Idan; Shpaisman, Hagay

doi:10.1039/c9cc05990c

Cited by 21 publications

(24 citation statements)

References 46 publications

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“…The combination of thermally driven reactions with microbubble assisted printing achieved simultaneous synthesis and printing of many materials such as SOMs, [ 178 ] ZnO, [ 179 ] Fe 2 O 3 , [ 177 ] oxidized Cu, [ 177 ] Ag, [ 177 ] Pt, [ 177 ] and RhAu nanoalloys. [ 180 ] More complex structures include the metal organic framework (MOF) FeBTC, [ 176 ] and combinations of SOMs with PANI and polypyrrole. [ 178 ] The minimal linewidths were ≈0.5–8 µm.…”

Section: Directed Local Synthesismentioning

confidence: 99%

“…The objective lenses used were 40×, [ 176,177 ] 50×, [ 176 ] and 100× [ 178–180 ] with NAs of 0.6 [ 176,177 ] and 1.3. [ 178,179 ] Laser wavelengths of 532 nm [ 176,177,180 ] and 1064 nm [ 178,179 ] were commonly used with powers between 0.6 and 50 mW. [ 176–180 ] The demonstrated stage velocities were 1–40 µm s −1 .…”

Section: Directed Local Synthesismentioning

confidence: 99%

“…[ 176–180 ] The demonstrated stage velocities were 1–40 µm s −1 . [ 176,177,179,180 ] Most studies assembled materials on glass substrates. [ 176–178,180 ] In some cases, to increase the absorption of the laser, the substrate was coated with an absorbing material such as Au [ 180 ] and ITO.…”

Section: Directed Local Synthesismentioning

confidence: 99%

“…However, recent studies demonstrated that microbubbles could play a major role in the deposition mechanism. [176][177][178][179][180] The temperature gradient around the bubble leads to natural and Marangoni convection currents (see Section 2.1.2). It was suggested that these currents in combination with capillary flow and evaporation of the liquid around the microbubble lead to an increase in ion concentration, [178,179] and even to supersaturation (Figure 8e).…”

Section: Variantsmentioning

confidence: 99%

“…Ringshaped depositions were obtained, which are characteristic of deposition around a microbubble (Figure 8g). [176][177][178] Better control over the size of the bubble, as well as preventing it from being pinned to the deposited material, can be achieved by laser modulation. [176,177] This is beneficial to the formation of continuous micro-patterns (Figure 8h and i).…”

Section: Variantsmentioning

confidence: 99%

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Laser‐Based Printing: From Liquids to Microstructures

Armon

Greenberg

Edri

et al. 2021

Adv Funct Materials

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Assembly of materials into microstructures under laser guidance is attracting wide attention. The ability to pattern various materials and form 2D and 3D structures with micron/sub‐micron resolution and less energy and material waste compared with standard top‐down methods make laser‐based printing promising for many applications, for example medical devices, sensors, and microelectronics. Assembly from liquids provides a smaller feature size than powders and has advantages over other states of matter in terms of relatively simple setup, easy handling, and recycling. However, the simplicity of the setup conceals a variety of underlying mechanisms, which cannot be identified simply according to the starting or resulting materials. This progress report surveys the various mechanisms according to the source of the material—preformed or locally synthesized. Within each category, methods are defined according to the driving force of material deposition. The advantages and limitations of each method are critically discussed, and the methods are compared, shedding light on future directions and developments required to advance this field.

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Section: Directed Local Synthesismentioning

confidence: 99%

Section: Directed Local Synthesismentioning

confidence: 99%

Section: Directed Local Synthesismentioning

confidence: 99%

Section: Variantsmentioning

confidence: 99%

Section: Variantsmentioning

confidence: 99%

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Laser‐Based Printing: From Liquids to Microstructures

Armon

Greenberg

Edri

et al. 2021

Adv Funct Materials

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Plasmonic Bubbles: From Fundamentals to Applications

Wang,

Dong

et al. 2024

Adv Funct Materials

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When illuminated by a resonant laser, noble metal nanoparticles immersed in liquids can efficiently produce a huge amount of heat and rapidly vaporize surrounding liquid, leading to the nucleation of plasmonic bubbles. Plasmonic bubbles are gaining increasing attention and emerged in numerous applications due to their unique properties and excellent controllability, such as microfabrication, micromanipulation, robot propulsion, molecule enrichment, and clinical therapies. In this review paper, the research progress of plasmonic bubbles in the past decade is summarized, including the plasmonic effect‐induced heat generation, experimental methods of plasmonic bubble observation, growth dynamics of plasmonic bubbles, approaches of optomechanical energy conversion via plasmonic bubbles, as well as their applications. This work provides a comprehensive understanding of the state of the art in the field and inspires researchers to explore more promising applications of plasmonic bubbles in different fields, like biology, microfluidics, and micromanufacturing.

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Engineering of the High‐Power Laser‐Induced Synthesis of Ni‐Based Metal‐Organic Framework: Investigation of its Optical Properties, Computational Methodology, Electrocatalytic Performances, and Glucose‐Sensing Ability

Mutlu,

Ortaç,

Karatutlu

et al. 2024

Adv Materials Technologies

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Metal‐organic frameworks (MOFs) are porous materials with numerous chemical and structural possibilities. Due to their ease of modification, well‐organized structure, and diverse guest molecule chemistry, MOFs are ideal platforms for uncovering improved functional material design characteristics. Quantitative analysis of glucose is crucial, especially in some food products, for quality control as well as evaluation of the glucose levels helps diagnose and treat diabetes. Recent glucose sensing devices have relied heavily on MOFs and other nanomaterials to enable user‐friendly and safe non‐invasive sensing methods. Nevertheless, the conventional synthesis methods involve multi‐day reactions, cooling, and depressurization processes. This study demonstrates the unprecedented high‐power laser‐induced rapid synthesis (LIRS) of Ni‐based MOF nanospheres with interconnected nano‐rods and noncentrosymmetric primitive triclinic crystalline structure, highlighting their multifunctional usage in sensing and gas sorption applications. Ab initio simulations show excellent agreement with the experimental physical and gas sorption properties. Furthermore, the Ni‐MOF‐based biosensor accurately measures glucose real‐life beverage samples, yielding promising glucose detection biosensor results with a low limit of the detection (LOD) of 13.96 µM and high sensitivity of 120.606 µA mM−1 cm−2.

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Simultaneous laser-induced synthesis and micro-patterning of a metal organic framework

Abstract: Micro-patterning of a metal organic framework (MOF) from a solution of precursors is achieved by local laser heating, alleviating the need for pre-preparation and stabilization.

Cited by 21 publications

References 46 publications

Laser‐Based Printing: From Liquids to Microstructures

Laser‐Based Printing: From Liquids to Microstructures

Plasmonic Bubbles: From Fundamentals to Applications

Engineering of the High‐Power Laser‐Induced Synthesis of Ni‐Based Metal‐Organic Framework: Investigation of its Optical Properties, Computational Methodology, Electrocatalytic Performances, and Glucose‐Sensing Ability

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