BACKGROUND: In industrial boilers, the flue gas temperature was below 200 ∘ C. The activated temperatures of conventional NO removal approach such as SCR was over 300 ∘ C, limiting its application in industrial boilers. In this study, a novel low-temperature NO removal approach with hydroxyl radicals (•OH) from catalytic decomposition of H 2 O 2 over La 1-x Ca x FeO 3 oxides (x = 0, 0.1, 0.3 and 0.5) was proposed. With respect to four as-prepared catalysts, the catalytic performance was presented and the mechanism was proposed.