2019
DOI: 10.1039/c9dt00558g
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Slow magnetization dynamics in a six-coordinate Fe(ii)–radical complex

Abstract: A mononuclear 6-coordinate hs-Fe(ii)–radical complex exhibits single-molecule magnet behaviour.

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Cited by 8 publications
(9 citation statements)
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“…31,32 Current examples of mononuclear transition metal-radical SMMs are limited to cobalt−nitroxide radical complexes, 33−35 cobalt−carbene radical complexes, 34−40 and an iron−dithiadiazolyl radical complex. 41 It is noteworthy that the magnitudes of the magnetic exchange interactions in these complexes are moderate (30 cm −1 < |J| < 70 cm −1 ).…”
Section: ■ Introductionmentioning
confidence: 87%
“…31,32 Current examples of mononuclear transition metal-radical SMMs are limited to cobalt−nitroxide radical complexes, 33−35 cobalt−carbene radical complexes, 34−40 and an iron−dithiadiazolyl radical complex. 41 It is noteworthy that the magnitudes of the magnetic exchange interactions in these complexes are moderate (30 cm −1 < |J| < 70 cm −1 ).…”
Section: ■ Introductionmentioning
confidence: 87%
“…Five representative crystal structures (codes: QUNQUM01, QUNQOG01, UDIPIH, TINQIT, and VOFHOQ) were then chosen, and the fragments displaying 2Ch–2N squares in these crystals are depicted in Figure . The fragment of QUNQUM01 is featured by two equivalent S···N contacts between a pair of Ph-DSDA radicals, leading to the formation of a square bonding motif.…”
Section: Resultsmentioning
confidence: 99%
“…Single-point calculations were undertaken here using the optimized geometries at the level of UM06-2X-D3/aug-cc-pVDZ. Five representative crystal structures (codes: QUN-QUM01, 37 QUNQOG01, 37 UDIPIH, 38 TINQIT, 16 and VOFHOQ 17 ) were then chosen, and the fragments displaying 2Ch−2N squares in these crystals are depicted in Figure 1.…”
Section: Methodsmentioning
confidence: 99%
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