Abstract. We measured δ 17 O and δ 18 O in two Antarctic ice cores at EPICA Dome C (EDC) and TALDICE (TD), respectively, and computed 17 O-excess with respect to VSMOW. The comparison of our 17 O-excess data with the previous record obtained at Vostok (Landais et al., 2008a) revealed differences up to 35 ppm in 17 O-excess mean level and evolution for the three sites. Our data show that the large increase depicted at Vostok (20 ppm) during the last deglaciation is a regional and not a general pattern in the temporal distribution of 17 O-excess in East Antarctica. The EDC data display an increase of 12 ppm, whereas the TD data show no significant variation from the Last Glacial Maximum (LGM) to the Early Holocene (EH). A Lagrangian moisture source diagnostic revealed very different source regions for Vostok and EDC compared to TD. These findings combined with the results of a sensitivity analysis, using a Rayleigh-type isotopic model, suggest that normalized relative humidity (RH n ) at the oceanic source region (OSR) is a determining factor for the spatial differences of 17 O-excess in East Antarctica. However, 17 O-excess in remote sites of continental Antarctica (e.g. Vostok) may be highly sensitive to local effects. Hence, we consider 17 O-excess in coastal East Antarctic ice cores (TD) to be more reliable as a proxy for RH n at the OSR.
Stable water isotopes in the hydrological cycleThe stable isotopes 2 H/H and 18 O/ 16 O ratios of water molecules in ice cores have been used for several decades as proxies for past temperature over the polar regions and have permitted the reconstruction of past climate changes over the last 800 ka (ka = thousand years before present) in Antarctica (Jouzel et al., 2007). Their link with temperature results from isotopic fractionation of water at each phase transition in the water cycle and especially along the water mass trajectory from the region of evaporation to the final polar precipitation site. The combination of δ 2 H and δ 18 O leads to the second order parameter d-excess = δ 2 H-8 δ 18 O (Dansgaard, 1964). It has been shown that d-excess in ice/snow from polar regions is mainly a function of temperature at the oceanic moisture source region (OSR) (Ciais and Jouzel, 1994;Petit et al., 1991), but it also depends on normalized relative humidity (RH n ) at the OSR (Jouzel et al., 1982), the surface ocean isotopic composition, wind speed and finally the temperature at the precipitation site (e.g. Stenni et al., 2001 andVimeux et al., 2002). The dependence of d-excess on these different parameters is variable from one site to another (Masson-Delmotte et al., 2008;Vimeux et al., 1999), and it is thus difficult to infer quantitative information on climatic conditions at the evaporative regions from d-excess alone.Published by Copernicus Publications on behalf of the European Geosciences Union.