2012
DOI: 10.5570/dfnd.en.1231.06
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Cited by 2 publications
(3 citation statements)
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“…Theo bserved homogeneous distribution of local carrier lifetimes across the perovskite film in our wide-field-illuminated PL measurements contradicts the results of recent confocal PL studies. [25][26][27][28][29] To understand the origin of this discrepancy,w ea lso collected the confocal PL image (with the same excitation intensity as in the wide-field illumination measurements) on the same area in the perovskite film (Figure 3d). We also observed grain-to-grain PL intensity (Figure 3d)a nd lifetime (Figure 3e)v ariations (with clearly faster kinetics in dark grains than in bright grains), even though these grains exhibit similar PL lifetime in the widefield illumination measurement (Figure 3b).…”
Section: Angewandte Chemiementioning
confidence: 99%
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“…Theo bserved homogeneous distribution of local carrier lifetimes across the perovskite film in our wide-field-illuminated PL measurements contradicts the results of recent confocal PL studies. [25][26][27][28][29] To understand the origin of this discrepancy,w ea lso collected the confocal PL image (with the same excitation intensity as in the wide-field illumination measurements) on the same area in the perovskite film (Figure 3d). We also observed grain-to-grain PL intensity (Figure 3d)a nd lifetime (Figure 3e)v ariations (with clearly faster kinetics in dark grains than in bright grains), even though these grains exhibit similar PL lifetime in the widefield illumination measurement (Figure 3b).…”
Section: Angewandte Chemiementioning
confidence: 99%
“…[24] Recent imaging studies have reported that PL or cathodoluminescence intensity and decay kinetics varied greatly (< 10 ns to 100 sns) from grain to grain and from grain interior to boundaries even in large-grained and high performing perovskite thin films. [25][26][27][28][29] These spatial variations of PL decays are attributed to aheterogeneous distribution of defects,w hich induce fast non-radiative carrier recombination, [25,28,29] and grain boundaries are believed to be the major regions with higher defect densities. [25] In contrary,some other theoretical and experimental studies also suggested that grain boundaries have negligible or even beneficial impact on the performance of perovskite solar cells.…”
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confidence: 99%
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