2019
DOI: 10.1016/j.dyepig.2018.08.018
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Solid-state acidochromic properties of barbituric acid-based 1,4-dihydropyridine derivatives with multiple coloured emissions switching

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Cited by 21 publications
(7 citation statements)
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“…Furthermore, some 1,4‐dihydropyridine derivatives reportedly exhibit solid‐state fluorescence color changes upon external stimuli such as exposure to pressure, acidic vapor, organic vapor, and heat. Namely, they exhibit mechanochromic (MC), acidochromic, vapochromic, and thermochromic properties, respectively . However, 1,4‐dihydropyridine derivatives that exhibit stimulus‐responsive activities in both the solid and solution state are rarely reported.…”
Section: Introductionmentioning
confidence: 70%
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“…Furthermore, some 1,4‐dihydropyridine derivatives reportedly exhibit solid‐state fluorescence color changes upon external stimuli such as exposure to pressure, acidic vapor, organic vapor, and heat. Namely, they exhibit mechanochromic (MC), acidochromic, vapochromic, and thermochromic properties, respectively . However, 1,4‐dihydropyridine derivatives that exhibit stimulus‐responsive activities in both the solid and solution state are rarely reported.…”
Section: Introductionmentioning
confidence: 70%
“…Namely,t hey exhibit mechanochromic (MC), acidochromic, vapochromic, and thermochromic properties, respectively. [22][23][24][25][26][27] However,1 ,4dihydropyridine derivatives that exhibit stimulus-responsivea ctivitiesi nb oth the solid and solution state are rarely reported.…”
Section: Introductionmentioning
confidence: 99%
“…According to the previous studies on the stimuli of the acid− base system, most of the mechanisms were attributed to the protonation and deprotonation in the process. 11,37,40 In order to further study the changes in the process of acid−base fumigation, the ligand HL was synthesized, and its crystal data are shown in Table S1 Interestingly, when ZnL 2 −HCl was fumigated with ethanol, the red film, which is attributed to HL on the surface, gradually faded (Figure S9a). Furthermore, it could be washed away by immersing in ethanol, and the crystal returned to a yellow color as well as the initial emission position, indicating a return to the initial state (Figure S9b).…”
Section: ■ Results and Discussionmentioning
confidence: 97%
“…Solid-state luminescent materials featuring stimuli-responses have attracted great interest due to their wide applications in the fields of sensors, optoelectronic devices, biomedical imaging, and security systems. Specifically, the stimuli-responsive materials with reversible luminescent color changes under external stimuli such as heating, vapors, or force have aroused great attention. , In particular, the high contrast luminous color or intensity is very important during the reversible process, which is convenient to be observed by the naked eye in practical applications. The structures of organic compounds are easy to be modified. The molecular interaction can be adjusted by changing the functional groups and the molecular aggregation mode to achieve the purpose of changing the luminescence properties.…”
Section: Introductionmentioning
confidence: 99%
“…In 2006, Peng et al synthesized fluorescent polymers with incorporated 1 H -pyridine-4-ylidene structural fragments. A detailed investigation of 4 H -pyran-4-ylidene-fragment-containing compounds with primary and secondary amines and well-defined evidence of 1 H -pyridine-4-ylidene derivative chemical structures by X-ray analysis were reported several years later. Recently, several 2,6-bis-styryl-substituted-1 H -pyridine-4-ylidene derivatives were successfully synthesized and reported as materials with aggregation-induced emission enhancement (AIEE) and multicolor switching properties. , Merocyanines are known for their prominent glass-forming and solid-state emission properties . While many J-aggregates usually exhibit strong fluorescence, the examples of a merocyanine H-aggregate exhibiting well-resolved emission with a longer fluorescence lifetime relative to that of the monomer was reported recently, proving the possibility of the usage of such kind of derivatives as materials exhibiting AIEE .…”
Section: Introductionmentioning
confidence: 99%