Solid-state mechanochemical synthesis of ferrocene

Makhaev, V. D.; Borisov, A. P.; Petrova, L. A.

doi:10.1016/s0022-328x(99)00460-x

Cited by 47 publications

(28 citation statements)

References 1 publication

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“…[256] Grinding (in an inert atmosphere) thallium cyclopentadienylide with iron or nickel dichlorides gave ferrocene and nickelocene respectively in good yields; potassium and sodium cyclopentadienylide did not give such good yields, but milling FeCl 2 with sodium methylcyclopentadienylide gave 1,1′-dimethylferrocene with 90% conversion. [257] Mechanochemistry may often prove useful in the conversion of inert and insoluble coordination polymers into more tractable molecules, by reaction with extra ligands that break up the polymeric structure. 4 ] with the elimination of chloride, [258] and Analogous reactions were also reported with basic zinc or copper carbonates [245] and palladium acetate.…”

Section: Ligand Addition Reactions With Elimination Of a By-productmentioning

confidence: 99%

Mechanochemistry: opportunities for new and cleaner synthesis

et al. 2012

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Citation for published item:tmesD F vF nd edmsD gF tF nd folmD gF nd frgD hF nd gollierD F nd pri § s § i¡ D F nd qrepioniD pF nd rrrisD uF hF wF nd ryettD qF nd tonesD F nd uresD eF nd wkD tF nd winiD vF nd yrpenD eF qF nd rkinD sF F nd herouseD F gF nd teedD tF F nd ddellD hF gF @PHIPA 9wehnohemistry X opportunities for new nd lener synthesisF9D ghemil soiety reviewsFD RI @IAF ppF RIQERRUF Further information on publisher's website: Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details.

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Section: Ligand Addition Reactions With Elimination Of a By-productmentioning

confidence: 99%

Mechanochemistry: opportunities for new and cleaner synthesis

et al. 2012

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“…The solvent-free synthesis of ferrocene by the mechanical milling of iron (II) chloride with (alkaline metals or thallium) cyclopentadienides (Table 1 -14) [50], and the synthesis of various ferrocenyl derivatives has been the focus of several research initiatives.…”

Section: Ferrocene and Ferrocenyl Compoundsmentioning

confidence: 99%

Organometallic chemistry in the melt phase

Bala

Coville

2007

Journal of Organometallic Chemistry

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“…[1,2,3,4] Ball mills provide one of the most common tools for mechanical stimulation of solid state processes such as phase transitions, [5,6,7] solid-solid reactions [8,9,10,11,12] decompositions, [13,14] as well as degradation [15,16,17] and amorphization [18] of polymers. Ball mills are capable of producing high strain fields that allow for initiating the aforementioned processes without heating.…”

Section: Statement Of the Problem Studiedmentioning

confidence: 99%

A Method of Monitoring Explosive Under Cyclic Mechanical Stress

Vyazovkin¹

2004

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Public Reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. 45489.1-EG-IIDynamic mechanical analysis is combined with mass spectrometry to study nitrocellulose under oscillating strain. At a constant temperature (150 -160°C) and frequency 400 -600 Hz nitrocellulose fractures demonstrating a modulus drop and release of products with m/z=30 and 44. At linear heating (2°C min-1) and frequency 10 -50 Hz similar products are released in two steps, the second of which demonstrates a modulus drop and a temperature increase indicating ignition. 8 Nitrocellulose, mechanodegradation, fractoemission, dynamic mechanical analysis, mass specrometry

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Solid-state mechanochemical synthesis of ferrocene

Cited by 47 publications

References 1 publication

Mechanochemistry: opportunities for new and cleaner synthesis

Mechanochemistry: opportunities for new and cleaner synthesis

Organometallic chemistry in the melt phase

A Method of Monitoring Explosive Under Cyclic Mechanical Stress

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