Solid-state synthesis of lanthanum-based oxides Co-coated LiNi0.5Co0.2Mn0.3O2 for advanced lithium ion batteries

Li, Lingjun; Xia, Lingfeng; Yang, Haoqi; Zhan, Xuehui; Chen, Jie; Chen, Zhaoyong; Duan, Junfei

doi:10.1016/j.jallcom.2020.154959

Cited by 58 publications

(15 citation statements)

References 29 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Lithium nickel manganese cobalt oxide (NMC) cathodes have been critical pillars of advanced lithium ion batteries at current state (Chen et al, 2019;Xu et al, 2019;Zhou et al, 2019;Kim et al, 2020;Li et al, 2020;Wang et al, 2020b;Wu et al, 2020;Zhang, 2020;Zheng et al, 2020). The particle's crystallinity and morphology can put significant influences on the energy density, cycling stability, and rate capability of the NMC cathodes in practical applications (Liu et al, 2018;Fan et al, 2020).…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Manipulation of Single-Crystalline Lithium Nickel Manganese Cobalt Oxide Cathodes: A Review of Growth Mechanism

et al. 2020

View full text Add to dashboard Cite

Lithium nickel manganese cobalt oxide (NMC) cathodes are of great importance for the development of lithium ion batteries with high energy density. Currently, most commercially available NMC products are polycrystalline secondary particles, which are aggregated by anisotropic primary particles. Although the polycrystalline NMC particles have demonstrated large gravimetric capacity and good rate capabilities, the volumetric energy density, cycling stability as well as production adaptability are not satisfactory. Well-dispersed single-crystalline NMC is therefore proposed to be an alternative solution for further development of high-energy-density batteries. Various techniques have been explored to synthesize the single-crystalline NMC product, but the fundamental mechanisms behind these techniques are still fragmented and incoherent. In this manuscript, we start a journey from the fundamental crystal growth theory, compare the crystal growth of NMC among different techniques, and disclose the key factors governing the growth of single-crystalline NMC. We expect that the more generalized growth mechanism drawn from invaluable previous works could enhance the rational design and the synthesis of cathode materials with superior energy density.

show abstract

Section: Introductionmentioning

confidence: 99%

Synthesis and Manipulation of Single-Crystalline Lithium Nickel Manganese Cobalt Oxide Cathodes: A Review of Growth Mechanism

et al. 2020

View full text Add to dashboard Cite

show abstract

“…Among these devices, due to high efficiency, zero-emission, and low noise, lithium batteries have attracted considerable attention and have already been used in various applications (Nishi, 2001 ; Goodenough and Kim, 2010 ). In the past few decades, energy density, rate capability, and cycling lifespan of lithium batteries have been significantly improved (Li et al, 2020 ; Sui et al, 2020 ; Wang et al, 2020b ; Luo et al, 2021 ), but still do not fully meet the requirements of electric vehicles (Lu et al, 2013 ) and smart-grids. In order to further improve the performance of lithium batteries, a deeper understanding of the working mechanisms at an atomic scale, which to a large extent are unknown, is desired.…”

Section: Introductionmentioning

confidence: 99%

Application of Reaction Force Field Molecular Dynamics in Lithium Batteries

Shi

Zhou

2021

Front. Chem.

View full text Add to dashboard Cite

Lithium batteries are widely used in portable electronic products. Although the performance of the batteries has been greatly improved in the past few decades, limited understanding of the working mechanisms at an atomic scale has become a major factor for further improvement. In the past 10 years, a reaction force field (ReaxFF) has been developed within the molecular dynamics framework. The ReaxFF has been demonstrated to correctly describe both physical processes and chemical reactions for a system significantly larger than the one simulated by quantum chemistry, and therefore in turn has been broadly applied in lithium batteries. In this article, we review the ReaxFF studies on the sulfur cathode, various anodes, and electrolytes of lithium batteries and put particular focus on the ability of the ReaxFF to reveal atomic-scale working mechanisms. A brief prospect is also given.

show abstract

“…Lithium-ion batteries (LIBs) have been widely used in portable electronics, electric vehicles, and large-scale energy storage systems owing to their high energy density, long cycling stability, and environmental friendliness (Armand and Tarascon, 2008 ; Yu et al, 2018 ; Zuo et al, 2019 ; Kwon et al, 2020 ; Li et al, 2020 ; Wang K. et al, 2020 ). Nowadays, the traditional commercial anode graphite (372 mAh g −1 ) is not able to meet increasing demands for higher energy density.…”

Section: Introductionmentioning

confidence: 99%

Pomegranate-Like Structured Si@SiOx Composites With High-Capacity for Lithium-Ion Batteries

Liu

Qiao

et al. 2020

Front. Chem.

View full text Add to dashboard Cite

Silicon anodes with an extremely high theoretical specific capacity of 4,200 mAh g −1 have been considered as one of the most promising anode materials for next-generation lithium-ion batteries. However, the large volume expansion during lithiation hinders its practical application. In this work, pomegranate-like Si@SiO x composites were prepared using a simple spray drying process, during which silicon nanoparticles reacted with oxygen and generated SiO x on the surface. The thickness of the SiO x layer was tuned by adjusting the drying temperature. In the unique architecture, the SiO x which serves as the protection layer and the void space in pomegranate-like structure could alleviate the volume expansion during repeated lithium insertion/extraction. As a lithium-ion battery anode, pomegranate-like Si@SiO x composites dried at 180 • C delivered a high specific capacity of 1746.5 mAh g −1 after 300 cycles at 500 mA g −1 .

show abstract

Solid-state synthesis of lanthanum-based oxides Co-coated LiNi0.5Co0.2Mn0.3O2 for advanced lithium ion batteries

Cited by 58 publications

References 29 publications

Synthesis and Manipulation of Single-Crystalline Lithium Nickel Manganese Cobalt Oxide Cathodes: A Review of Growth Mechanism

Synthesis and Manipulation of Single-Crystalline Lithium Nickel Manganese Cobalt Oxide Cathodes: A Review of Growth Mechanism

Application of Reaction Force Field Molecular Dynamics in Lithium Batteries

Pomegranate-Like Structured Si@SiOx Composites With High-Capacity for Lithium-Ion Batteries

Contact Info

Product

Resources

About