2007
DOI: 10.1021/ma062443e
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Soluble and Processable Phosphonate Sensing Star Molecularly Imprinted Polymers

Abstract: Soluble molecularly imprinted polymers (MIPs) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization followed by ring-closing metathesis (RCM). The polymerization was done in the presence of a template to generate a processable star MIP. The core of the star polymer was a dithiobenzoate-substituted tris(β-diketonate)europium(III) complex. The tris(β-diketonate)europium(III) complex served as a polymerization substrate for the three-armed RAFT-mediated star polymer and as a lumi… Show more

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Cited by 50 publications
(40 citation statements)
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“…St/SB [249] St/SB-b-MMA [249] 361 [250] 361-b-NIPAM [250] A See footnote A of Table 3. B See footnote B of Table 3.…”
Section: S Smentioning
confidence: 99%
“…St/SB [249] St/SB-b-MMA [249] 361 [250] 361-b-NIPAM [250] A See footnote A of Table 3. B See footnote B of Table 3.…”
Section: S Smentioning
confidence: 99%
“…Model systems employing β-diketone lanthanide complexes show luminescence enhancement with the addition of a variety of organophosphates. β-Diketones with fluorinated substituents were particularly effective [17,18,19]. The inclusion of β-diketones with aromatic rings was useful to shift absorbance from the UV to more easily accessible excitation wavelengths.…”
Section: Introductionmentioning
confidence: 99%
“…These materials have been employed in fields where a certain degree of selectivity is required such as chromatography [11,[16][17][18], sensors [19,20], immunoassays [21,22] and catalysts [23,24]. The most significant advantages of MIPs, as compared to biological receptors, such as antibodies, enzymes, nucleic acids, or cells, include their mechanical and chemical stability, high selectivity, low cost of preparation, and wide range of operating conditions [25,26].…”
Section: Introductionmentioning
confidence: 99%