2015
DOI: 10.1088/0953-2048/29/2/024002
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Solution design for low-fluorine trifluoroacetate route to YBa2Cu3O7films

Abstract: In the context of CSD-MOD growth of coated conductors for low cost and scalable production of YBCO coated conductors, new solutions are proposed in accordance with the new requirements concerning environmental safety and product performance. Looking at these objectives we will present here our work in the preparation of metallorganic precursor solutions with reduced fluorine content, which fulfill the requirements of superconducting YBCO epitaxial layers, leading to high superconducting performance. Solutions … Show more

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Cited by 45 publications
(83 citation statements)
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“…Conversely, although the XRD pattern of the present work is similar to [19], there are significant differences between our FTIR and XRD pattern and those reported in the literature [16][17][18][19], also there are significant differences among the different structures reported in the literature. Indeed, in carboxylates, the carboxylate bond and the crystalline structure depend strongly on the presence of crystallization water [2,[26][27][28], so that the distance between the asymmetric and symmetric carboxylic bands [Δν= ν as (COO…”
Section: Characterization Of Initial Productmentioning
confidence: 99%
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“…Conversely, although the XRD pattern of the present work is similar to [19], there are significant differences between our FTIR and XRD pattern and those reported in the literature [16][17][18][19], also there are significant differences among the different structures reported in the literature. Indeed, in carboxylates, the carboxylate bond and the crystalline structure depend strongly on the presence of crystallization water [2,[26][27][28], so that the distance between the asymmetric and symmetric carboxylic bands [Δν= ν as (COO…”
Section: Characterization Of Initial Productmentioning
confidence: 99%
“…Since in the presence of oxygen degradative oxidation is likely to take place, for films in a dry O 2 atmosphere decomposition can be triggered by the oxidation of the propionate groups to acetaldehyde, CO 2 and propionic acid to produce the reaction scheme shown in β (Hydrolysis + oxidation) of Fig. 1.…”
Section: Thermal Decomposition At Atmospheric Pressure: Organic Ligandmentioning
confidence: 99%
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