Solvent‐ and Metal‐free Oxidative Esterification of Aromatic Aldehydes Using Urea‐2,2‐dihydroperoxypropane as a New Solid Oxidant

Khosravi, Kaveh; Khalaji, Kobra; Naserifar, Shirin

doi:10.1002/jccs.201600777

Cited by 6 publications

(1 citation statement)

References 55 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In our recent work we have reported a solvent and metal free oxidative esterification of a multitude number of aromatic aldehydes in presence of HBr under mild acidic conditions in methanol …”

Section: Oxidative Esterification Of Aldehydes (Scheme Entry 9)mentioning

confidence: 99%

Urea‐2,2‐dihydroperoxypropane as a Novel and High Oxygen Content Alternative to Dihydroperoxypropane in Several Oxidation Reactions

Khosravi

Naserifar

2019

ChemistrySelect

Self Cite

View full text Add to dashboard Cite

Urea‐2,2‐dihydroperoxypropane (UDHPP)‐ a white crystalline solid oxidant which is formed when urea is recrystallized from dihydroperoxypropane‐ was applied as the terminal oxidant in several oxidative procedures namely epoxidation of α, β‐unsaturated ketones and alkenes, oxidation of sulfides to sulfoxides and sulfones, bayer‐villeger reaction, bromination and iodation of aniline and phenol derivatives, oxidative esterification, oxidative amidation of aromatic aldehydes, thiocyanation of aromatic compounds, and oxidation of pyridines, oxidation of secondary, allylic and benzylic alcohols. All the approaches were carried out under mild conditions and short reaction times and afforded the corresponding products in high yields.

show abstract

Section: Oxidative Esterification Of Aldehydes (Scheme Entry 9)mentioning

confidence: 99%

Urea‐2,2‐dihydroperoxypropane as a Novel and High Oxygen Content Alternative to Dihydroperoxypropane in Several Oxidation Reactions

Khosravi

Naserifar

2019

ChemistrySelect

Self Cite

View full text Add to dashboard Cite

show abstract

1,1,2,2-Tetrahydroperoxy-1,2-Diphenylethane: An efficient and high oxygen content oxidant in various oxidative reactions

Khosravi

Naserifar

2018

Tetrahedron

View full text Add to dashboard Cite

Advances for Catalysts in One-Step Oxidative Esterification of Aldehydes and Alcohols with Alcohols to Esters

Ding,

Su,

Shi

et al. 2024

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

Traditional esterification reactions usually take place between carboxylic acids or carboxylic acid derivatives and alcohols. How to produce ester efficiently and cleanly is an urgent problem that needs to be solved in ester industrial synthesis. The development of catalysts with high catalytic activity and a long service life is significant in this process. In this review, the recent advances of the catalysts in one-step oxidative esterification of aldehydes and alcohols with alcohols to esters are summarized, including heterogeneous (mainly Au-, Pd-, Co-, and Cu-based catalysts) and homogeneous catalysts. The preparation method, catalytic performance, and catalytic mechanism of each heterogeneous and homogeneous catalyst were introduced. Finally, we put forward the existing problems of the catalyst and provide strategies to solve them.

show abstract

Solvent‐ and Metal‐free Oxidative Esterification of Aromatic Aldehydes Using Urea‐2,2‐dihydroperoxypropane as a New Solid Oxidant

Abstract: Urea-2,2-dihydroperoxypropane as a noble and solid gem-dihydroperoxide derivative was used to transform various aromatic aldehydes to their corresponding benzoate derivatives in the presence of HBr under mild conditions at room temperature in high yields and short reaction times.

Cited by 6 publications

References 55 publications

Urea‐2,2‐dihydroperoxypropane as a Novel and High Oxygen Content Alternative to Dihydroperoxypropane in Several Oxidation Reactions

Urea‐2,2‐dihydroperoxypropane as a Novel and High Oxygen Content Alternative to Dihydroperoxypropane in Several Oxidation Reactions

1,1,2,2-Tetrahydroperoxy-1,2-Diphenylethane: An efficient and high oxygen content oxidant in various oxidative reactions

Advances for Catalysts in One-Step Oxidative Esterification of Aldehydes and Alcohols with Alcohols to Esters

Contact Info

Product

Resources

About