Solvent‐Dependent CN Bond Lengths in a Protonated Orthoamide

Köhn, R.; Seifert, Guido; Kociok‐Köhn, Gabriele

doi:10.1002/anie.199628791

Cited by 7 publications

(3 citation statements)

References 12 publications

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“…These isomers can be interconverted by changing the crystallization solvent. A similar solvent dependent system involving C-N bond lengths has been reported by Köhn et al 44 Although the effect of R on the structures is delineated in the present study, the exact role played by the substituent is not clear. Further, the formation of the two different structures 5 and 6 may not just be attributed to packing effects due to the different solvates in the crystal lattice.…”

Section: Discussionsupporting

confidence: 86%

Chemistry of thiocarboxylates: Synthesis and structures of neutral silver(I) thiocarboxylates with triphenylphosphine †

Deivaraj

Vittal

2001

J. Chem. Soc., Dalton Trans.

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Section: Discussionsupporting

confidence: 86%

Chemistry of thiocarboxylates: Synthesis and structures of neutral silver(I) thiocarboxylates with triphenylphosphine †

Deivaraj

Vittal

2001

J. Chem. Soc., Dalton Trans.

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“…For related compounds containing the [Cl 3 FeOFeCl 3 ] 2À anion, see: Yan et al (2000); Li et al (2008); Haselhorst et al (1993); Drew et al (1978); Ondrejkovicová et al (1998); James et al (1997); Kö hn et al (1997); Bullen et al (1986). For polynuclear iron(II/III) clusters, see: Pierre et al (1996); Proul-Curry & Chasteen (1995).…”

Section: Related Literaturementioning

confidence: 99%

Tris(1,10-phenanthroline)iron(II) μ-oxido-bis[trichloridoferrate(III)]

2011

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In the title salt, [Fe(C12H8N2)3][Fe2Cl6O], the ionic components are linked into a two-dimensional supramolecular layer by two pairs of C—H⋯Cl hydrogen bonds and π–π stacking interactions [centroid–centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent FeII–FeIII compound, in which an FeII atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two FeIII atoms in tetrahedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intramolecular C—H⋯N hydrogen bonds are observed.

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“…For literature relating to the intended product, see: Yoshida et al (2005); Zhong et al (2007). For literature relating to anions see: Molins et al (1998); Kohn et al (1996); Vasilevsky et al (1988).…”

Section: Related Literaturementioning

confidence: 99%

Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)]

2010

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In the title compound (C17H17N2)2[Fe2Cl6O], obtained from the solid-state reaction of FeCl2 and N,N′-dibenzylimidazolium chloride, the complex anion has approximate D 3d symmetry with crystallographically imposed inversion symmetry coincident with the bridging μ-O atom. The stereochemistry about each FeCl3O centre is distorted tetrahedral [Fe—Cl = 2.2176 (5)–2.2427 (5) Å and Fe—O = 1.7545 (2) Å]. The Cl atoms are involved in weak anion–cation C—H⋯Cl interactions, giving a network structure.

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Solvent‐Dependent CN Bond Lengths in a Protonated Orthoamide

Cited by 7 publications

References 12 publications

Chemistry of thiocarboxylates: Synthesis and structures of neutral silver(I) thiocarboxylates with triphenylphosphine †

Chemistry of thiocarboxylates: Synthesis and structures of neutral silver(I) thiocarboxylates with triphenylphosphine †

Tris(1,10-phenanthroline)iron(II) μ-oxido-bis[trichloridoferrate(III)]

Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)]

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