Solvent-driven structural topologies in phenanthroline-based co-crystals of Zn(ii) involving fascinating infinite chair-like {[(bzH)₄Cl₂]²⁻}_nassemblies and unconventional layered infinite {bz-H₂O-Cl}_nanion-water clusters: antiproliferative evaluation and theoretical studies

Abstract

Two new co-crystals of Zn(II) viz. [Zn(phen)3](bz)(Cl)•8H2O (1) and [Zn(phen)2(bz)](Cl)(2bzH) (2) (phen = 1,10-phenanthroline, bz = benzoate, bzH = benzoic acid) have been synthesized and characterized using single crystal X-ray...

Fumarato and phthalato bridged dinuclear metal–organic Cu(ii) and Mn(ii) compounds involving infinite fumarate–water assemblies and unusual structure-guiding H-bonded synthons: antiproliferative evaluation and theoretical studies

“…72 In the spectra of the compounds, the signals due to the –CH protons of the coordinated phen are observed at around 8.80 (H5), 8.38 (H4), 7.32 (H3) and 7.28 (H2) ppm. 73 Signals due to –CH protons of the phth moiety present in compound 2 appear at 7.47 (H6) and 7.28 (H1) ppm in the spectrum of the compound. 74 The 1 H-NMR data of the compounds are well consistent with the crystal structures revealing the stability of the compounds in the solution phase.…”