2018
DOI: 10.1002/polb.24619
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Solvent effects on the morphology and electrical conductivity of a D‐A random copolymer with low band gap

Abstract: D-A copolymer systems have unique characteristics, such as low band gap and ambipolar nature, which are important to design electronic polymer devices. In this contribution, we synthesized and characterized a D-A random copolymer containing bis-3-hexylthiophene-benzothiadiazole as acceptor unit and 9,9-dioctylfluorene as donor unit. We show that the polymeric film morphology depends of the Hansen solubility parameters, evaporation rate, and surface tension of the solvent. Chloroform, toluene, and 1,2,4-trichlo… Show more

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