1999
DOI: 10.1021/bk-1998-0713.ch001
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Solvent-Free Polymerizations and Processes: Recent Trends in the Minimization of Conventional Organic Solvents

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Cited by 5 publications
(8 citation statements)
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“…The absence of a solvent reduces the distance between molecules, favoring polymerization reactions. 38 On the other hand, the presence of water favors the proposed ring-opening hydrolysis of the desired bio-derived product, HMF, causing polymerization to humins. 16 As the final product of our reactions is humins, these conditions are not only with the greenest solvents (or absence of), but also can give visual images of what humins look like.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The absence of a solvent reduces the distance between molecules, favoring polymerization reactions. 38 On the other hand, the presence of water favors the proposed ring-opening hydrolysis of the desired bio-derived product, HMF, causing polymerization to humins. 16 As the final product of our reactions is humins, these conditions are not only with the greenest solvents (or absence of), but also can give visual images of what humins look like.…”
Section: Resultsmentioning
confidence: 99%
“…The experiments are designed with the best auxiliaries possible: no solvent and water. The absence of a solvent reduces the distance between molecules, favoring polymerization reactions . On the other hand, the presence of water favors the proposed ring-opening hydrolysis of the desired bioderived product, HMF, causing polymerization to humins .…”
Section: Resultsmentioning
confidence: 99%
“…[3][4][5][6][7] Generally, the development in green chemical processes can be divided into two scopes: reaction route alternatives [3][4][5] and solvent alternatives. [6][7][8] It is widely accepted that reducing the number of synthesis steps can significantly reduce the amount of waste and energy consumption. Hence, changing the reaction route to lower the number of synthetic steps is of significant environmental and economic advantage.…”
Section: Introductionmentioning
confidence: 99%
“…3 As well, alternative synthesis design and approaches utilizing green solvents for pollution prevention are highly desirable. [6][7][8] Regulation of the use of hazardous organic solvents is becoming increasingly stringent and has spurred the development of environmentally conscious, economical reaction media.…”
Section: Introductionmentioning
confidence: 99%
“…Solvent-free polymerization is an environmentally friendly method as it can eliminate the need for any solvent for polymerization. 24 The methodology of solvent-free polymerization has been introduced to chemical oxidative polymerizations, and vapor-phase chemical oxidative polymerization 25 27 and direct mixing chemical oxidative polymerization 28 , 29 have been developed. There are a few studies on solvent-free chemical oxidative polymerizations by mechanical mixing of monomer and solid oxidant.…”
Section: Introductionmentioning
confidence: 99%