2024
DOI: 10.1002/jrs.6656
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Spectroscopic characterization of extra‐framework hydrated proton complexes with the extremely strong hydrogen bonds in microporous silicate minerals

Nikita V. Chukanov,
Ramiza K. Rastsvetaeva,
Natalia V. Zubkova
et al.

Abstract: Microporous materials containing hydrated silanol groups Si–OH as well as hydrated proton complexes, H2n+1On+, including hydronium (n = 1), Zundel (n = 2), and Eigen (n = 4) cations, are of practical importance as potential ion exchangers and ion conductors. In this paper, we provide data on crystal‐chemical features, hydrogen bonding and Raman spectra of alkaline microporous titano‐, niobo‐, zircono‐, and aluminosilicate minerals belonging to the labuntsovite, lovozerite, eudialyte, and sodalite groups in whi… Show more

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