Spectroscopic, Thermal and Antimicrobial Study of Some Transition Metal(II) Complexes of β-Diketones

Abstract

A novel heterocyclic based β-diketone has been synthesized by the condensation of pyrazole-1-acetylchloride and sodium acetophenone. The product 1-phenyl-4-(pyrazole-1-yl)butane- 1,3-dione has been used for complexation with Mn(II), Fe(II) and Co(II) metal ions. The ligand β-diketone is found to exist in keto-enol tautomeric forms. The comparision of infrared spectra of complexes clearly indicates the coordination of the ligand from its enolic form. The magnetic moment and electronic spectra of all the metal complexes leads to the distorted octahedral symmetry around the metal ion. The ligand as well as its metal complexes has been screened for antimicrobial activity and antifungal activities. It is observed that the antimicrobial and antifungal activities get enhanced in complexes in respect to the free ligand.