“…Silver coordination polymers have attracted much attention not only because of the diverse coordination arrangement of the Ag I ion [1] but also the fascinating structural diversities and potential applications in many areas such as optics or electrical conductivity, magnetism, host-guest chemistry, and catalyst. The supra-molecular chemistry of the silver(I) coordination polymers represents a dynamic and thriving field which abounds with various supra-molecular forces such as Ag···ligand, Ag···Ag, Ag···π interactions [2][3][4][5][6][7] and various kinds of hydrogen bonds [including X-H···X, X-H···π, C-H···X, X-H···Ag (X = O, N, halogen), C-H···n (n: lone pair electrons) interactions], π···π stacking and anion interactions, although the closed d 10 configuration of silver(I) appears to cancel any inter-metallic bonding. [8][9][10][11][12][13][14][15][16][17][18] Triphenylphosphine (PPh 3 ) is a bulk and soft ligand.…”