1963
DOI: 10.1002/9780470143513.ch2
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Spectroscopy of Transition‐Group Complexes

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Cited by 192 publications
(30 citation statements)
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“…Splitting of the second 4 T g state because of the ground state JT effect is experimentally not observed. 77 Possible spin-forbidden transitions are to the two 2 A g , two 2 E g , and four 2 T g excited states. Promotion of the two electrons from the t g orbitals to the e g orbitals gives the one 4 A g state, one 2 E g , and two 2 T g states.…”
Section: F Excitation Energies Of D 7 Complex Ion: [Co(h 2 O) 6 ] 2+mentioning
confidence: 99%
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“…Splitting of the second 4 T g state because of the ground state JT effect is experimentally not observed. 77 Possible spin-forbidden transitions are to the two 2 A g , two 2 E g , and four 2 T g excited states. Promotion of the two electrons from the t g orbitals to the e g orbitals gives the one 4 A g state, one 2 E g , and two 2 T g states.…”
Section: F Excitation Energies Of D 7 Complex Ion: [Co(h 2 O) 6 ] 2+mentioning
confidence: 99%
“…Second, whether the experimental assignation of the spectrum of [Fe(H 2 O) 6 ] 3+ is appropriate. 7,20,21 The series of TM aqua complexes was chosen due to the vast number of experimental [67][68][69][70][71][72][73][74][75][76][77][78][79][80][81][82][83] and computational results 7,20,49,[84][85][86][87][88][89][90] available for the assessment of the success of both the methods. In addition to the comparison of the results to the spectroscopic studies, [74][75][76][77][78][79][80][81][82][83] attention is payed to the comparison of our results to the recent high-level ab initio calculations by Neese et al 7 and Schatz et al 20 that were performed on the same series of molecules.…”
Section: Introductionmentioning
confidence: 99%
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“…The starting point of crystal field multiplet theory is the approximation that the transition metal is an isolated ion with its electronic structure surrounded by a distribution of structure-less point charge sources, which mimic the symmetry around the central ion. Excellent textbooks on crystal field theory include Spectroscopy of Transition-Group Complexes [137] and Ligand Field Theory and the Properties of Transition Metal Complexes [186]. A recent review is Inorganic and Bioinorganic Spectroscopy [239].…”
Section: Theory B: Crystal Field Multiplet Theorymentioning
confidence: 99%
“…The starting point of crystal field multiplet theory is the approximation that the transition metal is an isolated ion with its electronic structure surrounded by a distribution of structure-less point charge sources, which mimic the symmetry around the central ion. Excellent textbooks on crystal field theory include Spectroscopy of Transition-Group Complexes [15] and Ligand Field Theory and the Properties of Transition Metal Complexes [16]. The effect of the cubic crystal field is that the seven 4f orbitals will lose their degeneracy and become split in energy into three distinct representations, respectively with T 1 , T 2 and A 2 symmetry.…”
Section: Detecting Crystal Field Effectsmentioning
confidence: 99%