2018
DOI: 10.1002/zaac.201800266
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Square Planar Coordination of Silver in a η4‐Cyclobutadiene‐(η5‐C5H5)ReBr2 Complex Framework

Abstract: Halide addition and abstraction experiments with the cationic rhenacyclopentatriene [(η5‐C5H5){ReC4(SBn)4}Br]BF4 and the side‐on cyclobutadiene complexes [(η5‐C5H5)(η4‐C4Ph4)ReX2] (X = Br, I), respectively, are described. Reversible interconversion of both coordination modes of the metal bonded C4R4 moiety depending on the presence or absence of the second bromide ligand is demonstrated for the sulfide derivative. However, formation of the [(η5‐C5H5)(ReC4Ph4)X]+ congener by halide abstraction at [(η5‐C5H5)(η4‐… Show more

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Cited by 3 publications
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References 39 publications
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