SRU TGTU Hydrogenation Catalyst Lifecycle Best Practices

Abstract

This report highlights the best practices captured in the management of Tail-Gas Treatment Unit (TGTU)’s hydrogenation CoMo catalyst throughout its lifecycle, these best practices were developed based on success story in operating the TGTU, which provides technical framework to manage TGTU unit performance throughout TGTU catalyst lifecycle. The aforementioned TGTU CoMo catalyst management best practices span across the whole catalyst lifecycle, starting from cradle stage of activating/sulphiding the fresh oxide-form catalyst up to grave stage of unloading & handling the spent catalyst to a safe location. Furthermore, stressing points have been provided to record special procedure to activate catalyst’s active sites (Cobalt & Molybdenum) in a process commonly known as “sulphiding”, as well as “passivation” procedure during TGTU catalyst unloading due to the presence of pyrophoric material such as Iron Sulphide (FeS) in the TGTU converter. This developed best practices provide solid reference point for future TGTU catalyst management throughout its lifecycle. Therefore, it can be adopted and consistently applied across other TGTU-based Sulfur Recovery Unit (SRU) plants in order to maintain the optimum Sulfur Recovery Efficiency (SRE), minimize plant downtime due to catalyst replacement and prevent unwanted environmental issues such as SO<sub>x</sub> emissions).