“…We think that the cross-linked enes behave like a new surface and may provide additional free energy term which makes the FLC molecules lie in a single potential minimum, 23,25,26) the position of which depends on the applied field, similar to the case of regular CDR switching FLCs. [27][28][29] We found that the sample does not show any memory behavior if the thiols are not bound to enes in the inter-layer space, even when the thiols in the intra-layer space are oriented parallel to LC molecules, as in the case of the unpolymerized sample. 23) Therefore, the thiols contribute to the memory behavior of samples only when they are in the intra-layer space parallel to the FLCs with one end bound to the polymerized enes in the inter-layer space.…”