Statistical assessment of operational parameters using optimized sulphonated titanium nanotubes incorporated sulphonated polystyrene ethylene butylene polystyrene nanocomposite membrane for efficient electricity generation in microbial fuel cell

Sugumar, Moogambigai; Dharmalingam, Sangeetha

doi:10.1016/j.energy.2021.123000

Cited by 13 publications

(5 citation statements)

References 81 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Despite all these advantages, Nafion ® membranes present some limitations i.e., ionconductivity drops rapidly in anhydrous conditions (RH < 80%) restricting the temperature to that not exceeding the boiling point of water and Nafion ® is an expensive material priced at about 500–700$ per m 2 [ 6 , 7 , 8 ]. So over the last few years, many alternative polymeric materials for PEM have been proposed which include sulfonated polyether ether ketone (sPEEK) [ 9 , 10 , 11 ], sulfonated polysulfone (sPSU) [ 12 , 13 ], sulfonated polyether sulfone (sPES) [ 14 , 15 , 16 ], polybenzimidazole (PBI) [ 17 , 18 , 19 ] and sulfonated polystyrene (sPS) [ 20 , 21 , 22 ]. In addition, many research groups have prepared composite PEMs using organic and inorganic fillers like TiO 2 , ZrO 2 , ZrP, BPO 4 , graphene oxide (GO), and SiO 2 to enhance the properties of proton exchange membranes [ 23 , 24 , 25 , 26 , 27 , 28 ].…”

Section: Introductionmentioning

confidence: 99%

Nanocomposite Membranes for PEM-FCs: Effect of LDH Introduction on the Physic-Chemical Performance of Various Polymer Matrices

2023

View full text Add to dashboard Cite

This is a comparative study to clarify the effect of the introduction of layered double hydroxide (LDH) into various polymer matrices. One perfluorosulfonic acid polymer, i.e., Nafion, and two polyaromatic polymers such as sulfonated polyether ether ketone (sPEEK) and sulfonated polysulfone (sPSU), were used for the preparation of nanocomposite membranes at 3 wt.% of LDH loading. Thereafter, the PEMs were characterized by X-ray diffraction (XRD) and dynamic mechanical analysis (DMA) for their microstructural and thermomechanical features, whereas water dynamics and proton conductivity were investigated by nuclear magnetic resonance (PFG and T1) and EIS spectroscopies, respectively. Depending on the hosting matrix, the LDHs can simply provide additional hydrophilic sites or act as physical crosslinkers. In the latter case, an impressive enhancement of both dimensional stability and electrochemical performance was observed. While pristine sPSU exhibited the lowest proton conductivity, the sPSU/LDH nanocomposite was able to compete with Nafion, yielding a conductivity of 122 mS cm−1 at 120 °C and 90% RH with an activation energy of only 8.7 kJ mol−1. The outcome must be ascribed to the mutual and beneficial interaction of the LDH nanoplatelets with the functional groups of sPSU, therefore the choice of the appropriate filler is pivotal for the preparation of highly-performing composites.

show abstract

Section: Introductionmentioning

confidence: 99%

Nanocomposite Membranes for PEM-FCs: Effect of LDH Introduction on the Physic-Chemical Performance of Various Polymer Matrices

2023

View full text Add to dashboard Cite

show abstract

“…The results were interesting, as they indicated that the rGOHI-AcOH-based catalysts, as mentioned earlier, could feasibly drive the MFC system without interruption (in terms of power density). The power output found in [116] was 76.6% higher than the maximum power output (138 mW/m 2 ) reported in a tubular MFC (T-MFC) [117]. The T-MFC was fabricated using a graphite rod as an anode electrode, carbon cloth-coated Pt (200 cm 2 ) as a cathode electrode, and nanocomposite as a proton exchange membrane.…”

Section: Bioelectricity Productionmentioning

confidence: 86%

An Overview of Microbial Fuel Cell Technology for Sustainable Electricity Production

Apollon

2023

Membranes

View full text Add to dashboard Cite

The over-exploitation of fossil fuels and their negative environmental impacts have attracted the attention of researchers worldwide, and efforts have been made to propose alternatives for the production of sustainable and clean energy. One proposed alternative is the implementation of bioelectrochemical systems (BESs), such as microbial fuel cells (MFCs), which are sustainable and environmentally friendly. MFCs are devices that use bacterial activity to break down organic matter while generating sustainable electricity. Furthermore, MFCs can produce bioelectricity from various substrates, including domestic wastewater (DWW), municipal wastewater (MWW), and potato and fruit wastes, reducing environmental contamination and decreasing energy consumption and treatment costs. This review focuses on recent advancements regarding the design, configuration, and operation mode of MFCs, as well as their capacity to produce bioelectricity (e.g., 2203 mW/m2) and fuels (i.e., H2: 438.7 mg/L and CH4: 358.7 mg/L). Furthermore, this review highlights practical applications, challenges, and the life-cycle assessment (LCA) of MFCs. Despite the promising biotechnological development of MFCs, great efforts should be made to implement them in a real-time and commercially viable manner.

show abstract

“…CM with sulphonic acid groups in the polymers displays improved ion transfer between electrodes. [70] This has led to the development of several PEM polymers with sulphonic acid groups such as Sulphonated Poly Ether Etherone, [68] Sulfonated Poly Styrene Ethylene Butylene Polystyrene, [71] Si-SPEEK, [72] sulfonated polysulfone (SPSF )73] , SPVC)/PAMPS, [74] Sulphonated polysilsesquioxanepolyimide [75] etc. As evident in this section, few studies are available discussing the fabrication and use of polymer-polymer composites for MFC.…”

Section: Polymer-polymer Composite Membranesmentioning

confidence: 99%

“…Besides the established advantage of its anti-biofouling nature in a membrane, Titanium in its sulphonated nanotubes version is hollow in structure enabling better water holding potential, facilitating Grotthus mechanism (by water molecules) and hopping mechanism (ion exchange group) for proton conductivity. [82] In another study using sulphonated TiO 2 nanotube (S-TNTs) with a polymer, Sugumar and Dharmalingam [71] fabricated Sulphonated Polystyrene Ethylene Butylene Polystyrene (SPSEBS) blended with different amounts of S-TNTs in composite membranes. The authors reported that SPSEBS + 6 % S-TNT displayed the highest proton conductivity, ion exchange capacity, water uptake, and a maximum power density of 138 mW/m 2 , suggesting better suitability for fuel cell performance.…”

Section: Metal/metal Oxide-polymer Compositesmentioning

confidence: 99%

Recent Advances in the Development of Sustainable Composite Materials used as Membranes in Microbial Fuel Cells

James,

Velayudhaperumal Chellam

2023

The Chemical Record

View full text Add to dashboard Cite

MFC can have dual functions; they can generate electricity from industrial and domestic effluents while purifying wastewater. Most MFC designs comprise a membrane which physically separates the cathode and anode compartments while keeping them electrically connected, playing a significant role in its efficiency. Popular commercial membranes such as Nafion, Hyflon and Zifron have excellent ionic conductivity, but have several drawbacks, mainly their prohibitive cost and non‐biodegradability, preventing the large‐scale application of MFC. Fabrication of composite materials that can function better at a much lower cost while also being environment‐friendly has been the endeavor of few researchers over the past years. The current review aims to apprise readers of the latest trends of the past decade in fabricating composite membranes (CM) for MFC. For emphasis on environmental‐friendly CM, the review begins with biopolymers, moving on to the carbon‐polymer, polymer‐polymer, and metal‐polymer CM. Lastly, critical analysis towards technology‐oriented propositions and realistic future directives in terms of strengths, weakness, opportunities, challenges (SWOC analysis) of the application of CM in MFC have been discussed for their possible large‐scale use. The focus of this review is the development of hybrid materials as membranes for fuel cells, while underscoring the need for environment‐friendly composites and processes.

show abstract

Statistical assessment of operational parameters using optimized sulphonated titanium nanotubes incorporated sulphonated polystyrene ethylene butylene polystyrene nanocomposite membrane for efficient electricity generation in microbial fuel cell

Cited by 13 publications

References 81 publications

Nanocomposite Membranes for PEM-FCs: Effect of LDH Introduction on the Physic-Chemical Performance of Various Polymer Matrices

Nanocomposite Membranes for PEM-FCs: Effect of LDH Introduction on the Physic-Chemical Performance of Various Polymer Matrices

An Overview of Microbial Fuel Cell Technology for Sustainable Electricity Production

Recent Advances in the Development of Sustainable Composite Materials used as Membranes in Microbial Fuel Cells

Contact Info

Product

Resources

About