Statistical thermodynamics of adsorption from multicomponent liquid mixtures on heterogeneous solid surfaces

Borówko, M.; Jaroniec, Mietek; Rudziński, W.

doi:10.1007/bf00906243

Cited by 23 publications

(1 citation statement)

References 21 publications

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“…It is no wonder that a relatively small number of papers deal with this problem. − , In the vast majority of published papers, solutions consisting of molecules of similar sizes have been considered. Theoretical model studies and interpretation of experimental data have been based on the well-known integral equation of the adsorption isotherm. , Apart from a few articles, , the topography of adsorption sites has been neglected.…”

Section: Introductionmentioning

confidence: 99%

A Monte Carlo Study of Adsorption from Mixtures of Dimers and Monomers on Heterogeneous Solid Surfaces

et al. 1997

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The results of a Monte Carlo simulation for adsorption from solutions of monomers and dimers on heterogeneous surfaces are presented. The adsorption and orientation of dimers adsorbed on surfaces of different (striplike and chessboard) topography are discussed. It is demonstrated that the surface topography has a considerable effect on the adsorption and orientation of dimers only when the size of the homotatic domains is smaller than the length of the adsorbed rodlike molecules. For larger patches, the adsorption does not depend strongly on the surface topography.

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Section: Introductionmentioning

confidence: 99%

A Monte Carlo Study of Adsorption from Mixtures of Dimers and Monomers on Heterogeneous Solid Surfaces

et al. 1997

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Adsorption of Rigid‐Rod Trimers from Liquid Mixture with Monomers on Heterogeneous Surfaces

Borówko

Rżysko

1997

Ber Bunsenges Phys Chem

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The results of Monte Carlo simulation for adsorption of linear trimers from their mixtures with monomers on homogeneous and heterogeneous surfaces are analysed. The lattice model of the liquid mixture is used. The different surface topographies (strip‐like and chess‐board) are considered. An influence of surface topography, size of homogeneous patches and molecular interactions on adsorption and orientational ordering in the mixed fluid near the boundary plane is discussed.

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Adsorption from binary solution in slit shaped pores

Borówko

Rżysko

1997

Ber Bunsenges Phys Chem

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A theoretical model for adsorption of a binary solution in a slit shaped pore is proposed. The classic lattice model of the solution is used. Adsorption systems exhibiting complete mixing are considered. The theoretical results are compared with Monte Carlo simulations in the grand canonical ensemble. An influence of pore size and nonideality of the liquid mixture on adsorption and selectivity is analysed.

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Statistical thermodynamics of adsorption from multicomponent liquid mixtures on heterogeneous solid surfaces

Cited by 23 publications

References 21 publications

A Monte Carlo Study of Adsorption from Mixtures of Dimers and Monomers on Heterogeneous Solid Surfaces

A Monte Carlo Study of Adsorption from Mixtures of Dimers and Monomers on Heterogeneous Solid Surfaces

Adsorption of Rigid‐Rod Trimers from Liquid Mixture with Monomers on Heterogeneous Surfaces

Adsorption from binary solution in slit shaped pores

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