Steering the electronic communication between Al/Ru bimetallic clusters in metal–organic framework composites for accelerating hydrogen evolution kinetics

Abstract

Synergistically modulating electron distribution between metal nodes in metal-organic frameworks (MOFs) is an effective strategy to improve the electrocatalytic performance of MOFs. Herein, a special bimetallic MOFs composite (Al0.35/Ru0.15-TCPP-CNTs) was...

Ampere-level oxygen evolution reaction driven by Co3O4 nanoparticles supported on layered TiO2

“…5a–c). 43 The d-band center ( ε d ) often dominates the progress of electrochemical reactions because it is directly related to the adsorption strength of the catalyst to reaction intermediates. According to the projected density of states (pDOS), it has been observed that attaching Co 3 O 4 on the TiO 2 surface tends to alter ε d (Fig.…”