Steric and electronic effects on Si–Ge bond lengths: An experimental and theoretical structural study of Me2Ge(SiCl3)2 and Me3GeSiCl3

Hinchley, Sarah L.; McLachlan, Lorna J.; Robertson, Heather E.; Rankin, David W. H.; Seppälä, Emma; Mont, Wolf‐Walther du

doi:10.1016/j.ica.2006.02.007

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Cited by 8 publications

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Germanimum: Organometallic Chemistry

Holl¹,

Peck²

2005

Encyclopedia of Inorganic Chemistry

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This article provides an overview of germanium organometallic chemistry from 1994 to 2007. Major advances in the formation and breaking of GeC bonds are discussed as are advances in the physical characterization of these compounds. Recent advances in the formation of organogermanium species containing multiple bonds to germanium and the formation of germanium‐centered radicals and cations are delineated. Applications to the synthesis of germanium‐containing polymers are overviewed.

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Germanimum: Organometallic Chemistry

Holl¹,

Peck²

2005

Encyclopedia of Inorganic Chemistry

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Germanimum: Organometallic Chemistry

Holl

Peck

2011

Encyclopedia of Inorganic and Bioinorganic Chemistry

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Tris(trichlorosilyl)tetrelide Anions and a Comparative Study of Their Donor Qualities

Teichmann

Kunkel

Georg

et al. 2019

Chemistry A European J

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Trichlorosilylated tetrelides [(Cl3Si)3E]− have been prepared by adding 1 equiv of a soluble Cl− salt to (Cl3Si)4Si (E=Si) or 4 Si2Cl6/GeCl4 (E=Ge). To assess their donor qualities, the anions [(Cl3Si)3E]− (E=C, Si, Ge) have been treated with BCl3, AlCl3, and GaCl3. Both BCl3 and GaCl3 give 1:1 adducts with the anionic centers. AlCl3 leads to Cl− abstraction from [(Cl3Si)3E]− with formation of (Cl3Si)4E (E=Si or Ge). (Cl3Si)4Ge is cleanly converted to the perhydrogenated (H3Si)4Ge by use of Li[AlH4]. Another case of Cl− abstraction was observed for [(Cl3Si)3Ge⋅GaCl3]−, which reacts with GaCl3 to afford the neutral dimer [(Cl3Si)3Ge−GaCl2]2.

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Steric and electronic effects on Si–Ge bond lengths: An experimental and theoretical structural study of Me2Ge(SiCl3)2 and Me3GeSiCl3

Cited by 8 publications

References 24 publications

Germanimum: Organometallic Chemistry

Germanimum: Organometallic Chemistry

Germanimum: Organometallic Chemistry

Tris(trichlorosilyl)tetrelide Anions and a Comparative Study of Their Donor Qualities

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