Sterically hindered amines for carbon dioxide removal from gases

Available online xxxx a b s t r a c tThe present review covers organic transformations involved in the reduction of CO 2 to chemical fuels. In particular, we focus on reactions of CO 2 with organic molecules to yield carboxylic acid derivatives as a first step in CO 2 reduction reaction sequences. These biomimetic initial steps create opportunities for tandem electrochemical/chemical reductions. We draw parallels between long-standing knowledge of CO 2 reactivity from organic chemistry, organocatalysis, surface science and electrocatalysis. We point out some possible non-faradaic chemical reactions that may contribute to product distributions in the production of solar fuels from CO 2 . These reactions may be accelerated by thermal effects such as resistive heating and illumination.

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“…Carbon dioxide has been shown to react with amines [46][47][48] (Eq. (4), 26) and related derivatives to form carbamates (27).…”

Section: Carbamates and Related Reductions (1)mentioning

confidence: 99%

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2 – The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates

Luca

Fenwick

2015

Journal of Photochemistry and Photobiology B: Biology

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“…In the early 1980s this concept was developed by Sartori and Savage (1983) and Savage et al (1984). Recently studies on the absorption rates of CO, into sterically hindered amines, specifically AMP, were presented by Chakraborty rt al.…”

Section: Alkanolaminesmentioning

confidence: 99%

Kinetics of the reaction of CO2 with the sterically hindered amine 2-Amino-2-methylpropanol at 298 K

Bosch

Versteeg

Swaaij

1990

Chemical Engineering Science

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Abstract-Absorptionrates of CO, into aqueous solutions of the sterically hindered amine AMP (2-_amino-Zmethylpropanol), under reaction-controlled conditions were measured. The experiments were carried out in a stirkd vessel with a smooth horizontal interface. The results were interpreted in terms of the zwitterion mechanism for the reaction of CO, with primary or secondary amines as originally proposed by Caplow (1968, J. Am. &em. Sot. 90,[6795][6796][6797][6798][6799][6800][6801][6802][6803] and Danckwerts (1979, Ch em. Engng Sci. 34,443446). The reaction rate constants and the equilibrium constant describing the stability ofthe carbamate of AMP were determined by fitting numerically calculated absorption rates to the experimentally observed ones. These constants were compared with data reported for AMP and with those for not sterically hindered amines.The relative values of the reaction rate constants could by explained only partially.

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“…For each sample, the heat capacity temperature and total amine concentration. The C P also difference, C P C Pa , was also obtained where C Pa is the heat capacity of the PZ-or salt-free solution calculated using (2) to (4) along with the parameters listed in Table I. As shown in An empirical model proposed by Sohnel and Novotny [28] was applied to represent the dependence of the C P of the aqueous ternary systems on temperature and solute (PZ or LiBr and AMPD) concentration.…”

Section: Resultsmentioning

confidence: 99%

“…It is defined, based on molecular structure, as a primary amine in which the amino group is attached to a tertiary carbon or a secondary amine in which the amino group is attached to at least one secondary or tertiary carbon [2], [3]. Due to the hindrance produced by the bulky group adjacent to its amino group, a sterically hindered amine forms unstable carbamate with CO 2 .…”

Section: Introductionmentioning

confidence: 99%

“…Due to the hindrance produced by the bulky group adjacent to its amino group, a sterically hindered amine forms unstable carbamate with CO 2 . This carbamate hydrolyses to bicarbonate and free amine, and increases the theoretical CO 2 loading to up to 1 mol of CO 2 per mol of amine [2]. It has been reported that 2-amino-2-methyl-1-propanol (AMP), which is the most popular sterically hindered amine, has CO 2 loading that is much higher than MEA, DEA, and TEA (triethanolamine) [4], [5].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Heat Capacities of Aqueous Ternary Mixtures of 2-Amino-2-Methyl-1, 3-Propanediol + Piperazine or Lithium Bromide

Olivia¹,

Leron²,

Li³

2014

IJCEA

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Abstract-In this work, we reported the molar heat capacities, C P , of aqueous solutions of the sterically hindered amines 2-amino-2-methyl-1, 3-propanediol (AMPD), and its aqueous ternaries containing piperazine (PZ) or lithium bromide (LiBr). Measurements were performed in the temperature range 303.15 K to 353.15 K and atmospheric pressure by heat flow differential scanning calorimetry. The excess molar heat capacities, C P E , of the binary solutions were determined, and the data were represented as function of temperature and composition using a RedlichKister-type equation. The C P of the ternary mixtures was correlated with temperature and amine concentration using the Sohnel and Novotny equation. Results showed that the calculated data agree very well with experimental C P values at average absolute deviation values of less than 0.2%. Index Terms-2-amino-2-methyl-1, 3-propanediol, molar heat capacity, redlichkister equation, sohnel and novotny equation.

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Sterically hindered amines for carbon dioxide removal from gases

Cited by 720 publications

References 1 publication

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2 – The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2 – The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates

Kinetics of the reaction of CO2 with the sterically hindered amine 2-Amino-2-methylpropanol at 298 K

Heat Capacities of Aqueous Ternary Mixtures of 2-Amino-2-Methyl-1, 3-Propanediol + Piperazine or Lithium Bromide

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