2015
DOI: 10.1016/j.steroids.2014.10.001
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Stimuli-responsive bile acid-based metallogels forming in aqueous media

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Cited by 13 publications
(19 citation statements)
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“…LCA , DCA , and CA amides were synthesized by following straightforward and facile literature methods (Scheme ) . All compounds were purified by simple recrystallizations with yields varying between 32 and 73 % (see Supporting Information for more details).…”
Section: Resultsmentioning
confidence: 99%
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“…LCA , DCA , and CA amides were synthesized by following straightforward and facile literature methods (Scheme ) . All compounds were purified by simple recrystallizations with yields varying between 32 and 73 % (see Supporting Information for more details).…”
Section: Resultsmentioning
confidence: 99%
“…[27,28] Several bile acid amide derivativesc ontaining af unctional group at the end of the aliphatic side chain have been reported and their properties studied by us. [29][30][31][32][33][34][35][36] Many of them have shownt ob ee ffective gelators, and one even formed stimuliresponsive metallogels. [34] Recently,w eh ave focusedo nt he bile acid derivatives that have no functional group at the end of the aliphatic side chain.…”
Section: Introductionmentioning
confidence: 99%
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“…56, compound 59) was found to self-assemble into a gel only in the presence of copper salt. 54 The copper salt solution was added to the aqueous solution of 59 containing methanol, acetone, or acetonitrile (30-50%). The molar ratios of 59 : salt were 2 : 1, 1 : 1, and 1 : 2, respectively.…”
Section: Stimuli-responsive Gelsmentioning
confidence: 99%
“…One of them is an aminoethyl amide analogue of the deoxycholic acid conjugated via an amide bond with picolinic acid(13) which turned out to gel upon addition of Cu 2+ ions in water in presence of 30-50% in volume of methanol, acetonitrile or acetone. Several reversible gel-sol transformations were observed such as by adding a variety of chemical species (EDTA, NH 4 OH, etc) and subjecting the system to mechanical stimuli (sonication and shaking) and Cu ion reduction[57]. Compound 14 is a good gelator in DMSO/water and DMF/water solutions and the gel-sol transformation is induced by acidifying the system[19**].…”
mentioning
confidence: 99%