“…30 In contrast, at high pulse energy, the DR was too high to complete the surface reconstruction, leading to the increased FWHMs with increasing pulse energy, completing the inverted bell-like shape of the FWHM. Iida et al 28,29 also reported epitaxial growth of Ba(Fe,Co) 2 As 2 films using a KrF excimer laser, but they need to use a Fe buffer layer to obtain good epitaxial films. This would be because that their laser power was in the range of 3-5 J/cm 2 , which is much lower than our optimum values (see Table I), and their substrate-to-target distance was longer (50 mm) than that of our PLD growth chamber (30 mm); therefore, we speculate that the above-discussed supersaturation regime is not attained due to the low density and the low kinetic energies of the deposition precursors, and consequently the Fe buffer layer is required to assist improved epitaxial growth.…”