Structural and Spectroscopic Aspects of Schiff Base Metal Complexes of Cobalt(II), Nickel(II) and Copper(II)

Rai, B.K.; Sinha, Puja; Singh, Vineeta; Vidhyarthi, S; Amit, Amit; Pandey, Ashok; Shahi, Shashi K.

doi:10.13005/ojc/300366

Cited by 5 publications

(2 citation statements)

References 3 publications

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“…During heating, a methanolic solution of nickel(II) acetate tetrahydrate salt with ( E )- N -methyl-2-(quinolin-2-ylmethylene)hydrazine-1-carbothioamide ( 83 ) dissolved in hot acetonitrile under stirring for 24 h at room temperature led to the formation of compounds bis-tridentate (hexadentate) nickel complex 84 in 84% yield ( Scheme 41 ) [ 96 ].…”

Section: Metal Complexes Of Thiosemicarbazones and Thiocarbazonesmentioning

confidence: 99%

Transition Metal Complexes of Thiosemicarbazides, Thiocarbohydrazides, and Their Corresponding Carbazones with Cu(I), Cu(II), Co(II), Ni(II), Pd(II), and Ag(I)—A Review

et al. 2023

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: This review focuses on some interesting and recent applications of transition metals towards the complexation of thiosemicarbazides, thiocarbohydrazides, and their corresponding carbazones. We started the review with a description of the chosen five metals, including Cu[Cu(I), Cu(II], Co(II), Ni(II), Pd(II), and Ag(I) and their electronic configurations. The stability of the assigned complexes was also discussed. We shed light on different routes describing the synthesis of these ligands. We also reported on different examples of the synthesis of Cu(I), Cu(II), Co(II), Ni(II), Ag(I), and Pd(II) of thiosemicarbazide and thiocarbohydrazide complexes (until 2022). This review also deals with a summary of the fruitful use of metal complexes of thiosemicarbazones and thiocarbazones ligands in the field of catalysis. Finally, this recent review focuses on the applications of these complexes related to their biological importance.

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Section: Metal Complexes Of Thiosemicarbazones and Thiocarbazonesmentioning

confidence: 99%

Transition Metal Complexes of Thiosemicarbazides, Thiocarbohydrazides, and Their Corresponding Carbazones with Cu(I), Cu(II), Co(II), Ni(II), Pd(II), and Ag(I)—A Review

et al. 2023

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“…In continuation of these series of investigation [7][8][9][10][11][12][13][14][15][16] -. The geometry of the complexes have been elucidated in the light of molar mass, elemental analysis, IR, electronic Spectra, molar conductance and magnetic susceptibility.…”

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Antimicrobial Activity of Co(II), Ni(II) and Cu(II) Coordination Compounds with Nitrogen, Oxygen Containing Schiff Base

K.¹,

Vidyarthi²,

Prakash³

et al. 2013

Orientjchem.

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Metal complexes of Schiff bases have played a significant role in the area of coordination compounds. The ligational behaviour of Schiff base towards the central metal ions provide versatility and extra stability of compound making a greater choice of flexibility.The chelating ability of analytical and biocidal application of Schiff bases have attracted remarkable attention [1][2][3][4][5][6] . In continuation of these series of investigation [7][8][9][10][11][12][13][14][15][16] -. The geometry of the complexes have been elucidated in the light of molar mass, elemental analysis, IR, electronic Spectra, molar conductance and magnetic susceptibility. The measured molar conductance value indicates that the complexes are non-electrolytic in nature. The above observation indicates that Schiff bases EHPQH behave as bidentate ligand and coordination proposes through azomethine N and oxygen atom of alcoholic group of ligand. The remaining coordination sites are satisfied by negative ion such as Ci -, Br -, I -and NB -. The geometry of the Co(II) and Ni(II) were proposed to be octahedral in geometry whereas Cu(II) complexes were proposed to be distorted octahedral. The Schiff bases and its complexes have been evaluated for their antibacterial activity. The complexes show enhanced antibacterial activity than ligand.

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Polyaniline-based electrocatalysts through emulsion polymerization: Electrochemical and electrocatalytic performances

Shehnaz

Song

Ren

et al. 2017

Journal of Energy Chemistry

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Structural and Spectroscopic Aspects of Schiff Base Metal Complexes of Cobalt(II), Nickel(II) and Copper(II)

Cited by 5 publications

References 3 publications

Transition Metal Complexes of Thiosemicarbazides, Thiocarbohydrazides, and Their Corresponding Carbazones with Cu(I), Cu(II), Co(II), Ni(II), Pd(II), and Ag(I)—A Review

Transition Metal Complexes of Thiosemicarbazides, Thiocarbohydrazides, and Their Corresponding Carbazones with Cu(I), Cu(II), Co(II), Ni(II), Pd(II), and Ag(I)—A Review

Antimicrobial Activity of Co(II), Ni(II) and Cu(II) Coordination Compounds with Nitrogen, Oxygen Containing Schiff Base

Polyaniline-based electrocatalysts through emulsion polymerization: Electrochemical and electrocatalytic performances

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