Structural Design and Simple Posttreatment of the Hole Transport Layer to Improve Performance of Hybrid Solar Cells

Abstract

The performance of organic‐inorganic hybrid solar cells (HSCs) can be improved by modifying the hole transport layer (HTL). Poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is the most active HTL material in organic‐inorganic HSCs and has been widely studied. Nevertheless, charge transfer in PEDOT:PSS is limited and inefficient due to the presence of the weak ionic conductor PSS. Moreover, the working function of the PEDOT:PSS film and the passivation of the PSS at the Si/PEDOT:PSS interface play a crucial role in carrier separation. The focus of this work is to explore a universal modification method to simultaneously achieve improved charge transport and interfacial passivation capability when using PEDOT:PSS as HTL. By combining bilayer design and simple solution posttreatment, the direct current conductivity (σdc) and work function of the HTL based on PEDOT:PSS are increased to 765 S cm−1 and 5.00 eV, respectively. The organic‐inorganic HSCs prepared using this approach achieve a photovoltaic conversion efficiency (PCE) of 12.33%, achieving a 16.54% improvement over untreated devices.