Structural Diversity and Chemical Trends in Hybrid Inorganic—Organic Framework Materials

Cheetham, Anthony K.; Rao, C. N. R.; Feller, Russell K.

doi:10.1002/chin.200708212

Cited by 27 publications

(37 citation statements)

References 1 publication

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“…He has suggested to consider the AMX 3 as simply as I 3 O 0 materials because these combine a network of an inorganic lattice with an organic species (molecular) based on a classification previously proposed by Rao et al . and Cheetham et al ., where I and O refer to inorganic and organic, respectively, and 3 and 0 refer to dimension three and zero, respectively. In fact, there are numerous compounds existing in the literature that have this combination, with the inorganic‐organic framework, which may or may not have the same chemical bonding topology.…”

Section: Discussionmentioning

confidence: 99%

Methylammonium Lead Trihalide Perovskite Solar Cell Semiconductors Are Not Organometallic: A Perspective

Varadwaj

2017

Helv. Chim. Acta

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Methylammonium lead trihalide perovskite solar cells (CH3NH3PbY3, where Y = I(3 − x)Brx = 1 – 3, I(3 − x)Clx = 1 – 3, Br(3 − x)Clx = 1 – 3, and IBrCl) are photonic semiconducting materials. Researches on various fundamental and technological aspects of these materials are extensively on‐going to make them stable environmentally and for commercialization. Research studies addressing these materials as organometallic are massively and repeatedly appearing in reputable and high‐profile peer‐reviewed journal publications (viz. Energy and Environmental Science, Nature Chemistry, Nature Communication, Advanced Materials, Science, ACS Nano, ACS Energy Letters, and in many other chemistry and materials based international journals). Herein, I candidly addresses the question: whether should scientists in the perovskite and nanomaterials science communities refer CH3NH3PbY3, as well as other perovskite derivatives falling into the same category, as organometallic?

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Section: Discussionmentioning

confidence: 99%

Methylammonium Lead Trihalide Perovskite Solar Cell Semiconductors Are Not Organometallic: A Perspective

Varadwaj

2017

Helv. Chim. Acta

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“…Metal‐organic frameworks (MOFs) have been proposed as a novel microporous material for gas storage and separation to develop clean energy applications. This is due to their inherent characteristics, such as high thermal stability, low density, high specific surface area, and a controllable structure .…”

Section: Introductionmentioning

confidence: 99%

Porous MOF‐205 with multiple modifications for efficiently storing hydrogen and methane as well as separating carbon dioxide from hydrogen and methane

Meng

Liu

et al. 2019

Int J Energy Res

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Summary In this work, quantum mechanical calculations and grand canonical Monte Carlo simulations were performed to study H2 and CH4 uptakes as well as CO2 separation from CH4 or H2 in MOF‐205 with different modification approaches. Upon C48B12 impregnation and Li decoration, B‐doped MOF‐205 shows remarkably improved gas adsorption and separation performances. Under ambient condition, both H2 and CH4 storage capacities in the modified materials meet the targets set by the US Department of Energy. Moreover, Li doping greatly increases the separation selectivity of CO2 in CO2/CH4 and CO2/H2 mixtures. This multiple modifications strategy opens the door to the production of porous nanomaterials with higher gaseous adsorption and separation capabilities.

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“…3 The possibility to isolate and heterogenize, into the inorganic matrixes, chiral, base, acid and/or redox centers, separated at controlled molecular distances, to perform in one-pot consecutive or cascade reactions is still in clear growth in materials science field. [4][5][6] Important advances has recently been carried out with the preparation of novel multi-functional organosiliceous materials or metalorganic structures capable to perform multi-component chiral reactions or multi-step processes catalyzed by only one recoverable hybrid solid catalyst in one-pot catalytic pathway. 7 However, in the majority of the cases, long reaction times, associated leaching phenomenon and low yield and stereoselectivity are observed.…”

Section: Introductionmentioning

confidence: 99%

Functional Acid and Base Hybrid Catalysts Organized by Associated (Organo)aluminosilicate Layers for C–C Bond Forming Reactions and Tandem Processes

2017

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Novel bifunctional acid-base monolayered hybrid catalysts (MLHMs), based on associated individual (organo)aluminosilicate sheets with amino and sulfonic pending groups located in the interlayer space, have been successfully prepared by direct alkaline hydrothermal synthesis and evaluated in consecutive catalytic transformations. Different characterization techniques such as chemical and thermogravimetrical analyses, X-ray diffraction, TEM microscopy, nuclear magnetic resonance (NMR), temperature programmed desorption of CO2 and NH3 (TPD), and textural measurements were used to show physico-chemical and structural nature of the materials, evidencing their effectivity as functional acid, base and acid-base catalysts for different one-pot two-step tandem reactions, which were performed in presence of only one active and recoverable lamellar-type hybrid solid catalyst.

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Structural Diversity and Chemical Trends in Hybrid Inorganic—Organic Framework Materials

Abstract: ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Cited by 27 publications

References 1 publication

Methylammonium Lead Trihalide Perovskite Solar Cell Semiconductors Are Not Organometallic: A Perspective

Methylammonium Lead Trihalide Perovskite Solar Cell Semiconductors Are Not Organometallic: A Perspective

Porous MOF‐205 with multiple modifications for efficiently storing hydrogen and methane as well as separating carbon dioxide from hydrogen and methane

Functional Acid and Base Hybrid Catalysts Organized by Associated (Organo)aluminosilicate Layers for C–C Bond Forming Reactions and Tandem Processes

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