2021
DOI: 10.1002/ejic.202100604
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Structural, Electronic, and Thermochemical Preference for Multi‐PCET Reactivity of Ruthenium(II)‐Amine and Ruthenium(IV)‐Amido Complexes

Abstract: The multiredox reactivity of bioinorganic cofactors is often coupled to proton transfers. Here we investigate the structural, thermochemical, and electronic structure of ruthenium-amino/ amido complexes with multi-proton-coupled electron transfer reactivity. The bis(amino)ruthenium(II) and bis(amido)ruthenium (IV) complexes [Ru II (bpy)(en*) 2 ] 2 + (Ru II -H 0 ) and [Ru IV (bpy)(en*-H 2 ) 2 ] 2 + (Ru IV -H 2 ) interconvert reversibly with the transfer of 2e À / 2H + (bpy = 2,2'-bipyridine, en* = 2,3-diamino-2… Show more

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