2017
DOI: 10.15261/serdj.24.105
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Structural Evaluation of the Aggregate of Palladium(II)-Pyridylazophenol Complex at the Heptane-Water Interface by the Centrifugal Liquid Membrane Method

Abstract: The formation and aggregation of the Pd(II) complex with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (HL) at the heptane-water interface was investigated by UV-vis absorption and resonance Raman spectrometry using the centrifugal liquid membrane (CLM) method. The interfacial aggregate had an absorption maximum wavelength at 488 nm, showing a hypsochromic shift from the absorption maximum wavelength at 580 nm of the complex monomer (PdLCl). The critical aggregation concentration of PdLCl was determined to be … Show more

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