Structural Study of the Conformational Isomers of(η4-Benzylideneacetone)- and (η4-Diene)Fe(CO)2LComplexes by Inverse Triple-Resonance Iron-57NMR

Rentsch, Gudrun Hopp; Nanz, Daniel; Solana, Isabel; Stefanova, Raina; Philipsborn, W. Von

doi:10.1002/(sici)1097-458x(199612)34:12<1036::aid-omr20>3.0.co;2-1

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2001

2009

Publication Types

Select...

Book4

Article1

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 7 publications

References 2 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Transition metal NMR chemical shifts and polarizability effect in organometallic complexes

Egorochkin

Кузнецова

Хамалетдинова

et al. 2009

Magnetic Reson in Chemistry

View full text Add to dashboard Cite

The literature data on substituent influence on the (51)V, (55)Mn, (57)Fe, (59)Co, (61)Ni, (95)Mo, (103)Rh, (183)W, (187)Os and (195)Pt NMR chemical shifts (delta) and on J (M, P; M = Mn, Fe, Mo, Rh, W, Os) coupling constants have been analyzed for 30 series of the organometallic complexes. It has been established for the first time that the delta and J values depend on the inductive, resonance and polarizability effects of substituents. The polarizability effect is caused by the partial charge on the central M atom. The contribution of this effect ranges from 3 to 86%.

show abstract