Structurally well-characterized zinc complexes bearing imine-benzotriazole phenoxide ligands: Synthesis, photoluminescent properties and catalysis for carbon dioxide/epoxide coupling

Chen, Ting Yi; Li, Chen Yu; Tsai, Chen‐Yen; Li, Chi Huan; Chang, Chia-Wen; Ko, Bao‐Tsan; Chang, Chia‐Chu; Lin, Chia Her; Huang, Hsi Ya

doi:10.1016/j.jorganchem.2013.12.030

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Cited by 16 publications

(1 citation statement)

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“…in diethyl ether. 9 The crystal structure of C83C BiIBTP-H 2 (Fig. S1, ESI †) displays two intramolecular hydrogen bonds for the O-H/N interaction exist between the phenol and aldimine groups.…”

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confidence: 99%

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

Chuang

et al. 2014

Polym. Chem.

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mentioning

confidence: 99%

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

Chuang

et al. 2014

Polym. Chem.

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PolymerizationCatalysis by Metal Phenolates

Dagorne

Romain

2016

Patai's Chemistry of Functional Groups

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Oxovanadium(V) catalysts for the CO₂ fixation into cyclic carbonates under ambient pressure

Chen

Liu

Tsai

2022

J Chinese Chemical Soc

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Developing feasible strategies to utilize CO2 as a C1 synthon for constructing various valued‐added chemical feedstock is crucial for alleviating the global warning and achieving a carbon‐neutral cycle. The coupling between epoxide and carbon dioxide is a promising direction due to the large driving force for the formation of thermodynamically stable cyclic carbonate and its 100% atom‐economy efficiency. Despite numerous metal‐based complexes that have been reported to facilitate this coupling reaction catalytically, harsh conditions (high temperature and pressure) are usually required. In this study, the synthesis and structural/spectroscopic characterizations of oxovanadium(V) complexes 2a–2f chelated with one‐step synthesized hydrazone‐imidate ligands were reported. The catalytic performance of the synthesized oxovanadium(V) complexes regarding the coupling reaction between epoxide and CO2 was successfully demonstrated with only 0.5 mol% loading of both oxovanadium(V) catalyst and [NBu4][Br] at 80°C under 1 bar of CO2. The substrate scope containing both terminal epoxide derivative and internal epoxide derivative indicates that the oxovanadium(V) catalysts could exert efficient catalytic coupling reaction of terminal epoxide (63 ~ 85% conversion rates) under ambient pressure of CO2.

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Structurally well-characterized zinc complexes bearing imine-benzotriazole phenoxide ligands: Synthesis, photoluminescent properties and catalysis for carbon dioxide/epoxide coupling

Cited by 16 publications

References 39 publications

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

PolymerizationCatalysis by Metal Phenolates

Oxovanadium(V) catalysts for the CO₂ fixation into cyclic carbonates under ambient pressure

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Structurally well-characterized zinc complexes bearing imine-benzotriazole phenoxide ligands: Synthesis, photoluminescent properties and catalysis for carbon dioxide/epoxide coupling

Cited by 16 publications

References 39 publications

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide

PolymerizationCatalysis by Metal Phenolates

Oxovanadium(V) catalysts for the CO2 fixation into cyclic carbonates under ambient pressure

Contact Info

Product

Resources

About

Oxovanadium(V) catalysts for the CO₂ fixation into cyclic carbonates under ambient pressure