Structure, morphology, thermal and electrochemical studies of electrochemically synthesized polyaniline/copper oxide nanocomposite for energy storage devices

Ashokkumar, S. P.; Yesappa, L.; Vijeth, H.; Niranjana, M.; Vandana, M.; Devendrappa, H.

doi:10.1088/2053-1591/ab5dde

Cited by 10 publications

(5 citation statements)

References 57 publications

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“…2b). A small strong peak was supported and indicates the thermal stability of PIC and SPIC nanocomposites which making it is well supported for TGA-DTA data [22][23][24].…”

Section: Thermal Analysissupporting

confidence: 58%

“…has shown an HRTEM image where 10 nm disclose the moon shape structure of AgNPs within the polymer matrix SPIC nanocomposites with small size. It could be revealed a larger dark surface (20 nm and 10 nm) with a more competent active center, which is a favourite of microbial activity [23]. The presence of a greater number of Cu metal ions has been indicated a thick dark region on the nanocomposite surface.…”

Section: Tem Morphologiesmentioning

confidence: 87%

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Evaluation of Antimicrobial, Structural, Magnetic, and Thermal Potential of Silver Nanoparticles Anchored Polyaniline-Itaconic Acid-CuO Nanocomposites Synthesized From In-Situ Polymerization Method

Parthiban¹,

Sudarsan²

2021

Preprint

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The silver nanoparticles (AgNPs) have been embedded within the itaconic acid (IA), polyaniline (PANi), and copper oxide (CuO) to form Ag@PANi-IA-CuO polymeric nanocomposites. In-situ polymerization of itaconic acid has been carried out in the presence of aniline monomers using anhydrous iron trichloride as an oxidising agent. The piper betel leaf extract was used to a reduction of AgNO3. The anchoring of AgNPs onto nanocomposite has been characterized using different techniques such as Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED) X-ray diffraction (XRD), and energy-dispersive X-ray (EDX). Biological, magnetic, and thermal properties of nanocomposites have also been studied in antimicrobial, vibrating sample magnetometer (VSM), and thermogravimetric analysis (TGA). Hence, these types of silver nanoparticles anchored polyaniline-itaconic acid-CuO nanocomposite has shown an attractive application in the field of biomedical and wastewater treatment.

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“…2b). A small strong peak was supported and indicates the thermal stability of PIC and SPIC nanocomposites which making it is well supported for TGA-DTA data [22][23][24].…”

Section: Thermal Analysissupporting

confidence: 58%

Section: Tem Morphologiesmentioning

confidence: 87%

Evaluation of Antimicrobial, Structural, Magnetic, and Thermal Potential of Silver Nanoparticles Anchored Polyaniline-Itaconic Acid-CuO Nanocomposites Synthesized From In-Situ Polymerization Method

Parthiban¹,

Sudarsan²

2021

Preprint

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“…Recently, Ashokkumar et al [214] synthesized PANI/CuO nanocomposite by an electrochemical deposition method. The concentration of CuO varied from 0.1 to 1 g, and homogenous dispersion of Cu ions in the PANI matrix was confirmed from SEM and TEM analyses.…”

Section: Metal Oxides and Pani Composites For Supercapacitorsmentioning

confidence: 99%

“…Recently, Ashokkumar et al [214] . synthesized PANI/CuO nanocomposite by an electrochemical deposition method.…”

Section: Metal Oxides and Pani Composites For Supercapacitorsmentioning

confidence: 99%

Recent Progress in Polyaniline and its Composites for Supercapacitors

Shah

Oladepo

Ehsan

et al. 2023

The Chemical Record

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Polyaniline (PANI) has piqued the interest of nanotechnology researchers due to its potential as an electrode material for supercapacitors. Despite its ease of synthesis and ability to be doped with a wide range of materials, PANI′s poor mechanical properties have limited its use in practical applications. To address this issue, researchers investigated using PANI composites with materials with highly specific surface areas, active sites, porous architectures, and high conductivity. The resulting composite materials have improved energy storage performance, making them promising electrode materials for supercapacitors. Here, we provide an overview of recent developments in PANI‐based supercapacitors, focusing on using electrochemically active carbon and redox‐active materials as composites. We discuss challenges and opportunities of synthesizing PANI‐based composites for supercapacitor applications. Furthermore, we provide theoretical insights into the electrical properties of PANI composites and their potential as active electrode materials. The need for this review stems from the growing interest in PANI‐based composites to improve supercapacitor performance. By examining recent progress in this field, we provide a comprehensive overview of the current state‐of‐the‐art and potential of PANI‐based composites for supercapacitor applications. This review adds value by highlighting challenges and opportunities associated with synthesizing and utilizing PANI‐based composites, thereby guiding future research directions.

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“…[22][23][24][25] However, limited investigations have been reported on the improvement of electrochemical performances of copper oxide-based SC electrode through hybridization with nanostructured CPs. The highest specific capacitance of 286, 198, and 20 F/g were reported for the CuO/polyaniline (PANi), 26,27 CuO/poly (3,4-ethylenedioxythiophene) (PEDOT) 26 and CuO/polypyrrole (ppy) 26 hybrid electrode, respectively. Gholivand et al 28 achieved the specific capacitance of 185 F/g together with 75% capacitance retention at 2000 cycles for the nanostructured CuO@PANiNFs nanocomposite.…”

Section: Introductionmentioning

confidence: 99%

Facile synthesis of copper oxide nanoparticles‐decorated polyaniline nanofibers with enhanced electrochemical performance as supercapacitor electrode

Ahmad

Anand

Fatima

et al. 2021

Polymers for Advanced Techs

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Copper oxide-decorated polyaniline nanofibers (CuO@PANiNFs) nanocomposite was prepared through in situ chemical deposition of CuO nanoparticles on the PANiNFs.The results of spectroscopic analyses suggested the presence of strong interfacial interactions between CuO nanoparticles and PANiNF matrix, while X-ray diffraction (XRD) analysis confirmed the formation of CuO monoclinic crystal phase on PAN-iNFs. SEM images displayed a uniform dispersion of CuO nanoparticles on the surface of PANiNFs. The highest specific capacitance of 486.9 F/g and area specific capacitance of 169 F/cm 2 at 0.5 mA/cm 2 were achieved for the CuO@PANiNFs nanocomposite. This could be ascribed to the low solution resistance and chargetransfer resistance of nanocomposite electrode as observed in the electrical impedance spectroscopic results. The CuO@PANiNFs electrode revealed good cyclic stability with $82% capacitance retention after 2000 cycles. The CuO@PANiNFs electrode delivered a maximum energy density of 67.7 Wh/kg, which is nearly 1.8 times higher than that of the pure PANiNFs electrode. Therefore, the present CuO@PANiNFs nanocomposite with high specific capacitance and energy density could be used as a cost-effective, ecofriendly, and sustainable supercapacitor electrode material.

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Structure, morphology, thermal and electrochemical studies of electrochemically synthesized polyaniline/copper oxide nanocomposite for energy storage devices

Cited by 10 publications

References 57 publications

Evaluation of Antimicrobial, Structural, Magnetic, and Thermal Potential of Silver Nanoparticles Anchored Polyaniline-Itaconic Acid-CuO Nanocomposites Synthesized From In-Situ Polymerization Method

Evaluation of Antimicrobial, Structural, Magnetic, and Thermal Potential of Silver Nanoparticles Anchored Polyaniline-Itaconic Acid-CuO Nanocomposites Synthesized From In-Situ Polymerization Method

Recent Progress in Polyaniline and its Composites for Supercapacitors

Facile synthesis of copper oxide nanoparticles‐decorated polyaniline nanofibers with enhanced electrochemical performance as supercapacitor electrode

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