Structure of Three Related Diphosphorus Ligands: Highlighting the Significance of the Backbone

Marimuthu, Thashree; Bala, Muhammad D.; Friedrich, Holger B.

doi:10.1007/s10870-011-0233-1

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“…For related structures, see: ; ; Tooke et al (2005); Pintado-Alba et al (2004). For additional information on hemilabile ligands, see: Dallanegra et al (2012); Marimuthu et al (2012); Tello-Ló pez (2010).…”

Section: Related Literaturementioning

confidence: 99%

“…Metal complexes of hemilabile ligands have been studied in the last few years due to their importance in homogeneous catalysis Dallanegra et al, 2012;Marimuthu et al, 2012). The phosphine derivatives (Ia,b), (IIa-d), and (IIIa-f) are a set of hemilabile ligands where the nature of the heteroatoms determines their coordinating ability towards soft or hard metals ( Fig.…”

Section: Data Collectionmentioning

confidence: 99%

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(2-{[2-(diphenylphosphino)phenyl]thio}phenyl)diphenylphosphine sulfide

et al. 2012

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Key indicators: single-crystal X-ray study; T = 296 K; mean (C-C) = 0.005 Å; R factor = 0.059; wR factor = 0.135; data-to-parameter ratio = 19.4.In the title compound, C 36 H 28 P 2 S 2 , the dihedral angle between the central benzene rings is 66.95 (13) . In the crystal, molecules are linked via C ar -HÁ Á Á and -interactions [shortest centroid-centroid distance between benzene rings = 3.897 (2) Å ]. Related literature

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Section: Related Literaturementioning

confidence: 99%

Section: Data Collectionmentioning

confidence: 99%