Structure, physical, chemical and photophysical properties of Pt(bph) (CO)2, where bph is the biphenyl dianion

Dibenzometallacyclopentadienes, boroles and selected transition metal and main group heterocyclopentadienes: Synthesis, catalytic and optical properties

“…Photophysical properties of several Pt [21,23,41,42] and Pd [21,43] 2,2 -biphenyl complexes have been reported. These are of interest with regard to possible use in OLEDs and other luminescent applications which require accessible triplet states, cf.…”

“…15), by reaction of 2,2 -dilithiobiphenyl with [ZrCl 2 Cp 2 ] [19]. This method has also been used for the synthesis of Pd [20,21] and other Pt [22,23] from [PtCl 2 (SEt 2 ) 2 ] and [PtCl 2 (CO) 2 ], the former group having synthesized a planar Pt 2 (SEt 2 ) 2 bridged species 26 and the latter group observing mononuclear [Pt(2,2 -bph)(CO) 2 ] (27) (Fig. 16).…”

“…the now popular 2-phenylpyridine complexes mentioned in the Introduction [3,4]. Rillema and co-workers have extensively studied the absorption and emission properties of a number of Pt(2,2 -bph) complexes with the mono-and bidentate ligands, pyridine, acetonitrile, ethylenediamine, CO (27) [23,42], dppm [44,45], and the bridging ligand SEt 2 [41]. Absorption spectra of mono-metallic [Pt(2,2 -bph)(py) 2 ] (52), [Pt(2,2 -bph)(NCMe) 2 ] bonyl complex 27 have been carried out to examine singlet and triplet excited states, and to compare calculated geometries with those from the X-ray crystallographic data previously obtained [42,43].…”

“…Examples of Pt(2,2 -bph) complexes formed from Pt chloride salts and 2,2 -dilithiobiphenyl; molecular structure of 27 in the solid state[22,23].…”

Platinum organometallic compounds: classification and analysis of crystallographic and structural data. Part I. Monomeric Pt(0) and partly of Pt(II) with PtC4, PtA3B and PtC2A2 chromophores

“…There are 14 derivatives , Browning et al 1975, Barker et al 1976, Golberg et al 1977 Brought to you by | New York University Bobst Library Technical Services Authenticated Download Date | 5/31/15 3:34 AM 1986a, Kemmitt et al 1989, Yamamoto and Yamazaki 1989, Dryden et al 1994, Felhammer et al 1994, Chen et al 1995, Kernbach and Felhammer 1995 in which four C atoms create the square planar environment about each Pt(II) atom. The colourless derivative (Golberg et al 1977 ) uses four C(NHMe) 2 ligands and the pale yellow derivative (Us ó n et al 1984(Us ó n et al , 1986a four C 6 Cl 5 ligands to create a nearly ideal square planar geometry around Pt(II) atoms.…”