Structure, spectroscopic measurement, thermal studies and optical properties of a new hybrid compound of aquapentachloroindoidate(III) complex

Preparation, molecular structure, vibrational and photoluminescence study of a novel compound based chlorocadmate (II) material

“…MEP is generated using the Avogadro software [29], on an asymmetric unit. The MEP is used as reactivity map displaying most probable regions for the electrophilic Attack of charged point-like reagents on hybrid molecules [30,31]. The blue and red colors indicate the positive and negative potentials, respectively.…”

Two Zero‐Dimensional In3+‐Based Hybrid Halides: Single‐Component Materials Showing Bluish‐White‐Light Emission

“…Such as organic‐inorganic halide hybrids (OIHs), [11–13] all‐inorganic semiconductor nanocrystals, [14] organic/polymeric emitters [15–17] and so on, [18–21] many materials with broadband emission characteristics have been discovered. As one of these candidates, OIHs have been considered to be competitive, owing to their tunable structure and photoluminescence features [22–25] . The molecular scale bonding or interpenetrating network creation of the inorganic and organic phases in OIHs leads to the formation of different dimensional structures, including zero, one, two or three dimension (0, 1, 2 or 3D) [26–29] .…”

“…As one of these candidates, OIHs have been considered to be competitive, owing to their tunable structure and photoluminescence features. [22][23][24][25] The molecular scale bonding or interpenetrating network creation of the inorganic and organic phases in OIHs leads to the formation of different dimensional structures, including zero, one, two or three dimension (0, 1, 2 or 3D). [26][27][28][29] It has been proved that the distortion in low dimensional (1D or 2D) structures are more likely to capture excitons and form phototransient defects, [30] for example, AMPPbX 4 , [31] (N-AEP) 2 Pb 2 Cl 10 ⋅ H 2 O, [32] AQPbCl 4 , [33] (N-MEDA)[PbBr 4 ], [34] etc.…”

Two Lead‐Free Organic‐Inorganic Hybrid Halides: Exploring Dielectric Switching and Photoluminescence Integrated in Crystals

“…It is worth noting that organic‐inorganic hybrid halides (OIHs), can integrate switchable dielectric and photoluminescence properties in one compound [15–17] . Such materials are convenient for design because of their structural tunability, in which the inorganic and organic phases are combined by a bond or an interpenetrating network construction on the molecular scale, [18,19] forming structures of different dimensions [20–23] . This feature of OIHs is attractive, due to their assistance for researchers in adjusting and predicting the properties of materials [24,25] .…”