Structure, Thermal Behavior, and Vibrational Spectroscopy of the Silver Borate AgB₃O₅

Abstract

The new silver borate AgB 3 O 5 was obtained under highpressure, high-temperature conditions at 3 GPa and 600°C in a Walker-type multianvil device. The compound crystallizes with four formula units (Z = 4) in the unit cell in the orthorhombic space group Pna2 1 (no. 33). The lattice parameters are a = 1029.7(2), b = 832.2(2), c = 390.00(8) pm, and V = 0.3342(2) nm 3 . The new non-centrosymmetric structure is built up from planar BO 3 groups and BO 4 tetrahedra, which are interconnected by two-and threefold-coordinated

Ag[B(SO4)2] – Synthesis, Crystal Structure, and Characterization of the First Precious‐Metal Borosulfate

“…ver borates SrAg[B 7 O 12 ] [12] and CsAg 2 [B 15 O 24 ]. [13] Although two further silver borates AgB 3 O 5 [14] and Ag 3 B 5 O 9 [15] have been discovered, similarly to Pd(B 2 O 4 ), these compounds are also exclusively accessible by simultaneously applying high temperature and high pressure.…”

RbB11O16(OH)2: First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System

“…In general, the incorporation of the (OH) group in borate can avoid the appearance of terminal oxygen atoms and decrease the dimension of the BÀ O framework. According to the references, [53][54][55][56][57][58][59][60] it can be known that the isolated anionic groups of those hydroxyl rubidium borates except Rb 3 2 ]⋅0.5H 2 O, its FBB contains two terminal oxygen atoms, and the FBBs are connected together through common vertex to form a 1D chain. And in the title compound, its FBB contains four terminal oxygen atoms, which can combine other ones through sharing oxygen atoms to form the anionic framework with higher dimension.…”

“…As a result, the upsurge in the exploration of new crystals has been triggered. [1][2][3][4] After many studies, some crystals with potential applications have been produced, including borate, [5][6][7][8][9][10][11] phosphate, [12][13][14][15][16] vanadate, [17][18] carbonate, [19][20][21][22] and so on. [23][24][25] During the process of exploring new crystals, the researchers paid much attention on borates due to their wide applications as nonlinear optical (NLO) materials, [26][27][28][29][30] birefringent materials, [31] and so on.…”

Novartis Chemistry Lectureship 2014–2015: R. Sarpong, A. Doyle, M. S. Sigman, F. Glorius, D. Trauner, and K. R. Liedl / Karl Heinz Beckurts Prize: A. Marx / Polymer Networks Group Young Investigator Award: D. Díaz Díaz, J. Groll, F. H. Schacher, and S. Seiffert

“…Leidl’s research program is focused on the physics‐based understanding of biomolecular interfaces by computer simulations and quantum mechanics. He is co‐author of reports in Angewandte Chemie on the spectroscopic observation of matrix‐isolated carbonic acid,6a and in the European Journal of Organic Chemistry on the properties of the silver borate AgB 3 O 5 6b …”