Structures and Properties of Keratin-Based and Related Biological Materials

The methylimidazolium chloride ionic liquid (IL) was successfully used for the dissolution of cotton cellulose. IL and IL-cellulose were investigated by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy analyses. The obtained IL-cellulose was applied to wool and hair keratin fiber surfaces, forming a fine coating layer. From FT-IR and XRD analyses, the results suggested the reduction of hydrogen bonds and crystallinity in IL-cellulose-coated wool fibers. This effect was caused by covering the wool with the IL-cellulose coating, and good intrinsic mechanical properties were observed. Moreover, the dimensional performance of coated keratin fibers presented length variations of around 8 and 12% under wet and dry conditions for wool and hair fibers, respectively. Coated keratin fibers could be of great value for a cleaner process in the cosmetic area associated with their ability to stretch and curl when triggered by humidity.

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Poly(lactide)-Based Materials Modified with Biomolecules: A Review

Świerczyńska,

Kudzin,

Chruściel

2024

Materials

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Poly(lactic acid) (PLA) is characterized by unique features, e.g., it is environmentally friendly, biocompatible, has good thermomechanical properties, and is readily available and biodegradable. Due to the increasing pollution of the environment, PLA is a promising alternative that can potentially replace petroleum-derived polymers. Different biodegradable polymers have numerous biomedical applications and are used as packaging materials. Because the pure form of PLA is delicate, brittle, and is characterized by a slow degradation rate and a low thermal resistance and crystallization rate, these disadvantages limit the range of applications of this polymer. However, the properties of PLA can be improved by chemical or physical modification, e.g., with biomolecules. The subject of this review is the modification of PLA properties with three classes of biomolecules: polysaccharides, proteins, and nucleic acids. A quite extensive description of the most promising strategies leading to improvement of the bioactivity of PLA, through modification with these biomolecules, is presented in this review. Thus, this article deals mainly with a presentation of the major developments and research results concerning PLA-based materials modified with different biomolecules (described in the world literature during the last decades), with a focus on such methods as blending, copolymerization, or composites fabrication. The biomedical and unique biological applications of PLA-based materials, especially modified with polysaccharides and proteins, are reviewed, taking into account the growing interest and great practical potential of these new biodegradable biomaterials.

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Structures and Properties of Keratin-Based and Related Biological Materials

Cited by 3 publications

References 17 publications

Extraction and application of keratin from natural resources: a review

Extraction and application of keratin from natural resources: a review

Cellulose Dissolved in Ionic Liquids for Modification of the Shape of Keratin Fibers

Poly(lactide)-Based Materials Modified with Biomolecules: A Review

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