“…There is substantial number of theoretical studies, showing 42 the strong predominance of the enol-keto form (1EK) in 1 and curcumin-like structures. 43 Additionally, 1EK is the tautomeric form existing in solid state [9]. In solution the tautomerism 44 of 1 has been studied by NMR [17,18], IR [5,10], UV-Vis absorption [11], and emission 45 [11,12,13,14,15,16] spectroscopies, showing that in most solvents the enol-keto tautomer is the 46 only existing one.…”