2017
DOI: 10.1021/acs.inorgchem.7b00029
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Studies on the Activation and Hydrosilylation Catalysis of RhCl3(Bu2S)3

Abstract: RhCl(BuS) is an industrial precatalyst utilized in the curing of some solventless silicone-release coatings formulations. The catalyst requires no additional inhibitor, in contrast to typical Pt formulations, and so questions arose about how fast the catalyst could trigger curing if it were used in a more activated form. Studies on the activation of RhCl(BuS) revealed multiple intermediates, of which [RhCl(BuS)] and [RhHCl(SiMe(OSiMe)) (BuS)] were isolated. [RhHCl(SiMe(OSiMe))(BuS)] is the most activated form … Show more

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