2012
DOI: 10.1016/j.synthmet.2012.08.014
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Studies on the conducting nanocomposite prepared by polymerization of 2-aminobenzoic acid with aniline from aqueous solutions in montmorillonite

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Cited by 15 publications
(8 citation statements)
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“…In the N1s spectra of PANI sample, the peak at 398.5 eV (black line) corresponds to quinoid imine (–N=), and the more prominent peak at 399.5 eV (red line) corresponds to benzenoid amine (–NH–) in the PANI backbone . An additional two minor peaks at 400.8 eV and 402.2 eV (blue and dark cyan lines) correspond to positively charged imine in the bipolaron state and protonated amine in the polaron state . These spectra demonstrate the typical structure of the PANI in ES form.…”
Section: Resultsmentioning
confidence: 74%
“…In the N1s spectra of PANI sample, the peak at 398.5 eV (black line) corresponds to quinoid imine (–N=), and the more prominent peak at 399.5 eV (red line) corresponds to benzenoid amine (–NH–) in the PANI backbone . An additional two minor peaks at 400.8 eV and 402.2 eV (blue and dark cyan lines) correspond to positively charged imine in the bipolaron state and protonated amine in the polaron state . These spectra demonstrate the typical structure of the PANI in ES form.…”
Section: Resultsmentioning
confidence: 74%
“…Intercalated and/or exfoliated nanocomposites can be prepared by intercalation polymerization depending on the monomer/clay ratio. In the past, PANI/Clay nanocomposites were synthesized by emulsion intercalation [17][18][19], electrochemical [20,21], inverse emulsion polymerization [22], in situ intercalation [23][24][25][26][27], and mechanochemical intercalation method [28,29]. A higher intercalation level of PANI inside the clay gallery was achieved when the clay was chemically modified by various organic molecules before the polymerization [30,31].…”
Section: Introductionmentioning
confidence: 99%
“…Any organic-inorganic hybrid materials can be 26 obtained by intercalative reactions of layered solids based on 27 self-assembly approaches [11][12][13][14]. 28 Recently, on the basis of conducting polymers and inorganic 29 nanoparticles, the nanocomposites have attracted attention as it 30 seems to be the potential route to improve the performance of 31 materials in devices. Several reports on the synthesis of the 32 nanocomposites of polyaniline with Fe 3 O 4 [15], ZnO [16], ZrO 2 [17], 33 TiO 2 [18] and montmorillonite [19] nanoparticles have already 34 been published.…”
mentioning
confidence: 99%