“…The family Orchidaceae is divided into 5 subfamilies, i.e., Epidendroideae, Orchidoideae, Vanilloideae, Cypripedioideae, and Apostasioideae [ 44 ]. So far, dimeric phenanthrenes have been reported from only two subfamilies, i.e., Epidendroideae (the genera Stanhopea, Bletilla, Pholidota, Pleione, Otochilus, Arundina, Bulbophyllum, Dendrobium, Monomeria, Cremastra, Agrostophyllum, Liparis, Cyrtopodium , Eria , Eulophia , Cirrhopetalum , Calanthe, Lusia, and Prosthechea ) and Orchidoideae (the genera Spiranthes and Gymnadenia ) [ 34 , 39 , 45 , 46 , 47 , 48 , 49 , 50 , 51 , 52 , 53 , 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , 62 , 63 ]. No biphenanthrenes have been found outside these two subfamilies.…”