Studies on the intermolecular interactions in the binary mixtures of nitrobenzene with 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol and 2-butoxyethanol at<i>T</i> = 298.15 K

Kinart, Cezary M.; Ćwiklińska, Aneta; Kinart, Zdzisław; Bald, Adam; Kinart, Wojciech J.

doi:10.1080/00319104.2012.712971

Cited by 21 publications

(3 citation statements)

References 56 publications

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“…Again, the experimental viscosity of liquid mixtures has been correlated with the following six different theoretical models of single and double adjustable parameters [16][17][18][19][20][21], Grunberg-Nissan,…”

Section: Resultsmentioning

confidence: 99%

“…Hence, it becomes of considerable interest to compute viscosity in liquid mixtures by applying various mathematical models and to identify the suitable relation for the studied liquid mixtures. As a continuation of our effort [11,12], dynamic viscosities of binary system: Tri-n-butyl phosphate (TBP) + benzene are estimated by using different mathematical relations of zero, one and two adjustable parameters [13][14][15][16][17][18][19][20][21] at 308.15K and then comparing the computed values of viscosities with that of the experimentally measured values. Our survey of the literature shows that there have not been any theoretical viscosity data reported for the binary system of TBP with benzene.…”

Section: Introductionmentioning

confidence: 99%

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Viscosity modelling of tri-n-butyl phosphate + benzene mixtures at 308.15K

2020

Biointerface Res Appl Chem

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Dynamic viscosities () of a binary liquid system: Tri-n-butyl phosphate (TBP) + benzene have been experimentally measured over the entire range (X1) of TBP at temperature 308.15K and pressure 0.1MPa. The dynamic viscosity of liquid mixtures hasbeen calculated using five mathematical relations of zero adjustable parameters such as Croenaurer-Rothfus- Kermore relation, Gambrill relation, Bingham relation, Kendall-Munroe relation and Arrhenius – Eyring relation. The validity of these relations has been verified separately by taking the average percentage deviations (APD) and root mean square deviation relative (RMSDs) between experimental and computed values and displayed graphically. Furthermore, the mixture viscosities have been correlated with those predicted one by using another six models of single and double adjustable / interaction parameters such as Grunberg-Nissan, Katti and Chaudhri, Hind, Tamura -Kurata, Heric and Eyring-Margules. A comparison between theoretical and experimental values of viscosity divulges that Gambrill’s relation predicts the data reasonably well in case of zero adjustable parameters whereas Eyring-Margules shows the best fit in case of single and double interaction parameters.

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Viscosity modelling of tri-n-butyl phosphate + benzene mixtures at 308.15K

2020

Biointerface Res Appl Chem

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“…The probable error in mole fraction was estimated to be less than ± 2.10 -4 . The detailed procedure for measurements of ultrasonic velocity, density and viscosity of liquid mixtures are the same as described elsewhere [8,9]. The density () of the ternary mixture was measured using a specific gravity bottle (25 ml) by relative mass measurement method.…”

Section: Properties Measurementsmentioning

confidence: 99%

Acoustic assessment in binary mixtures of a polar nuclear extractant, DEHPA with eight non polar diluents at 303.15K – a comparative study

2020

Biointerface Res Appl Chem

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Ultrasonic velocities (U), viscosities (η) and densities (ρ) of binary liquid mixtures of di–(2-ethylhexyl) phosphoric acid (DEHPA) with eight non polar diluents viz. n-pentane, n-hexane, n-heptane, benzene, carbon tetrachloride, cyclohexane, carbon disulphide and dioxane are measured at temperature 303.16 K and 0.01MPa for entire range of concentration. The measured data are used to compute acoustic impedance (Z), isentropic compressibility, intermolecular free length, free volume, internal pressure and viscous relaxation time. The excess properties are also evaluated from the measured data to study inter- and intra-molecular interaction between components of liquid mixtures. The research findings may be utilized in solvent extraction process to enhance extraction efficacy.

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Viscosity of the binary liquid mixture of 2-methoxyethanol and nitrobenzene

Wohlfarth¹

2017

Viscosity of Pure Organic Liquids and Binary Liquid Mixtures

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Studies on the intermolecular interactions in the binary mixtures of nitrobenzene with 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol and 2-butoxyethanol atT = 298.15 K

Cited by 21 publications

References 56 publications

Viscosity modelling of tri-n-butyl phosphate + benzene mixtures at 308.15K

Viscosity modelling of tri-n-butyl phosphate + benzene mixtures at 308.15K

Acoustic assessment in binary mixtures of a polar nuclear extractant, DEHPA with eight non polar diluents at 303.15K – a comparative study

Viscosity of the binary liquid mixture of 2-methoxyethanol and nitrobenzene

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